(N→B)-4-Methyl-3-pyrid­yl[N-methyl­imino­diacetate-O,O′,N]borane

The title compound, C(11)H(13)BN(2)O(4), has a rigid bicyclic structure due to an intra­molecular nitro­gen–boron dative bond. The B atom is in a distorted tetra­hedron environment with a B—N bond length of 1.640 (2) Å, which is in good comparison with the values in analogues compounds. In the cryst...

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Detalles Bibliográficos
Autores principales: Dąbrowski, Marek, Durka, Krzysztof, Serwatowski, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515177/
https://www.ncbi.nlm.nih.gov/pubmed/23284404
http://dx.doi.org/10.1107/S1600536812040974
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author Dąbrowski, Marek
Durka, Krzysztof
Serwatowski, Janusz
author_facet Dąbrowski, Marek
Durka, Krzysztof
Serwatowski, Janusz
author_sort Dąbrowski, Marek
collection PubMed
description The title compound, C(11)H(13)BN(2)O(4), has a rigid bicyclic structure due to an intra­molecular nitro­gen–boron dative bond. The B atom is in a distorted tetra­hedron environment with a B—N bond length of 1.640 (2) Å, which is in good comparison with the values in analogues compounds. In the crystal, the mol­ecules are linked by weak C—H⋯O and C—H⋯N inter­actions, forming a three-dimensional network.
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spelling pubmed-35151772013-01-02 (N→B)-4-Methyl-3-pyrid­yl[N-methyl­imino­diacetate-O,O′,N]borane Dąbrowski, Marek Durka, Krzysztof Serwatowski, Janusz Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(11)H(13)BN(2)O(4), has a rigid bicyclic structure due to an intra­molecular nitro­gen–boron dative bond. The B atom is in a distorted tetra­hedron environment with a B—N bond length of 1.640 (2) Å, which is in good comparison with the values in analogues compounds. In the crystal, the mol­ecules are linked by weak C—H⋯O and C—H⋯N inter­actions, forming a three-dimensional network. International Union of Crystallography 2012-10-06 /pmc/articles/PMC3515177/ /pubmed/23284404 http://dx.doi.org/10.1107/S1600536812040974 Text en © Dąbrowski et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dąbrowski, Marek
Durka, Krzysztof
Serwatowski, Janusz
(N→B)-4-Methyl-3-pyrid­yl[N-methyl­imino­diacetate-O,O′,N]borane
title (N→B)-4-Methyl-3-pyrid­yl[N-methyl­imino­diacetate-O,O′,N]borane
title_full (N→B)-4-Methyl-3-pyrid­yl[N-methyl­imino­diacetate-O,O′,N]borane
title_fullStr (N→B)-4-Methyl-3-pyrid­yl[N-methyl­imino­diacetate-O,O′,N]borane
title_full_unstemmed (N→B)-4-Methyl-3-pyrid­yl[N-methyl­imino­diacetate-O,O′,N]borane
title_short (N→B)-4-Methyl-3-pyrid­yl[N-methyl­imino­diacetate-O,O′,N]borane
title_sort (n→b)-4-methyl-3-pyrid­yl[n-methyl­imino­diacetate-o,o′,n]borane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515177/
https://www.ncbi.nlm.nih.gov/pubmed/23284404
http://dx.doi.org/10.1107/S1600536812040974
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