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2-Methyl-3-(4-methylphenyl)-5,6-diphenyl-2,3-dihydropyrazine
In the title molecule, C(24)H(22)N(2), four atoms (N—C—C—N) of the heterocyclic ring, with their attached H atoms, and all atoms of the methyl group, are disordered over two positions; the site-occupancy factor of the major component is 0.713 (6). The major disorder component of the heterocyclic ri...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515189/ https://www.ncbi.nlm.nih.gov/pubmed/23284416 http://dx.doi.org/10.1107/S1600536812041438 |
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author | Thiruvalluvar, A. Anuradha, N. Chitra, S. Devanathan, D. Butcher, R. J. |
author_facet | Thiruvalluvar, A. Anuradha, N. Chitra, S. Devanathan, D. Butcher, R. J. |
author_sort | Thiruvalluvar, A. |
collection | PubMed |
description | In the title molecule, C(24)H(22)N(2), four atoms (N—C—C—N) of the heterocyclic ring, with their attached H atoms, and all atoms of the methyl group, are disordered over two positions; the site-occupancy factor of the major component is 0.713 (6). The major disorder component of the heterocyclic ring adopts a half-chair conformation, with all substituents equatorial. The benzene ring adjacent to the methyl group forms dihedral angles of 79.68 (11) and 80.92 (11)° with the phenyl rings; the dihedral angle between adjacent phenyl rings is 59.10 (11)°. The crystal structure features three C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3515189 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35151892013-01-02 2-Methyl-3-(4-methylphenyl)-5,6-diphenyl-2,3-dihydropyrazine Thiruvalluvar, A. Anuradha, N. Chitra, S. Devanathan, D. Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(24)H(22)N(2), four atoms (N—C—C—N) of the heterocyclic ring, with their attached H atoms, and all atoms of the methyl group, are disordered over two positions; the site-occupancy factor of the major component is 0.713 (6). The major disorder component of the heterocyclic ring adopts a half-chair conformation, with all substituents equatorial. The benzene ring adjacent to the methyl group forms dihedral angles of 79.68 (11) and 80.92 (11)° with the phenyl rings; the dihedral angle between adjacent phenyl rings is 59.10 (11)°. The crystal structure features three C—H⋯π interactions. International Union of Crystallography 2012-10-06 /pmc/articles/PMC3515189/ /pubmed/23284416 http://dx.doi.org/10.1107/S1600536812041438 Text en © Thiruvalluvar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Thiruvalluvar, A. Anuradha, N. Chitra, S. Devanathan, D. Butcher, R. J. 2-Methyl-3-(4-methylphenyl)-5,6-diphenyl-2,3-dihydropyrazine |
title | 2-Methyl-3-(4-methylphenyl)-5,6-diphenyl-2,3-dihydropyrazine |
title_full | 2-Methyl-3-(4-methylphenyl)-5,6-diphenyl-2,3-dihydropyrazine |
title_fullStr | 2-Methyl-3-(4-methylphenyl)-5,6-diphenyl-2,3-dihydropyrazine |
title_full_unstemmed | 2-Methyl-3-(4-methylphenyl)-5,6-diphenyl-2,3-dihydropyrazine |
title_short | 2-Methyl-3-(4-methylphenyl)-5,6-diphenyl-2,3-dihydropyrazine |
title_sort | 2-methyl-3-(4-methylphenyl)-5,6-diphenyl-2,3-dihydropyrazine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515189/ https://www.ncbi.nlm.nih.gov/pubmed/23284416 http://dx.doi.org/10.1107/S1600536812041438 |
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