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2-Methyl-3-(4-methyl­phen­yl)-5,6-diphenyl-2,3-dihydro­pyrazine

In the title mol­ecule, C(24)H(22)N(2), four atoms (N—C—C—N) of the heterocyclic ring, with their attached H atoms, and all atoms of the methyl group, are disordered over two positions; the site-occupancy factor of the major component is 0.713 (6). The major disorder component of the heterocyclic ri...

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Autores principales: Thiruvalluvar, A., Anuradha, N., Chitra, S., Devanathan, D., Butcher, R. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515189/
https://www.ncbi.nlm.nih.gov/pubmed/23284416
http://dx.doi.org/10.1107/S1600536812041438
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author Thiruvalluvar, A.
Anuradha, N.
Chitra, S.
Devanathan, D.
Butcher, R. J.
author_facet Thiruvalluvar, A.
Anuradha, N.
Chitra, S.
Devanathan, D.
Butcher, R. J.
author_sort Thiruvalluvar, A.
collection PubMed
description In the title mol­ecule, C(24)H(22)N(2), four atoms (N—C—C—N) of the heterocyclic ring, with their attached H atoms, and all atoms of the methyl group, are disordered over two positions; the site-occupancy factor of the major component is 0.713 (6). The major disorder component of the heterocyclic ring adopts a half-chair conformation, with all substituents equatorial. The benzene ring adjacent to the methyl group forms dihedral angles of 79.68 (11) and 80.92 (11)° with the phenyl rings; the dihedral angle between adjacent phenyl rings is 59.10 (11)°. The crystal structure features three C—H⋯π inter­actions.
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spelling pubmed-35151892013-01-02 2-Methyl-3-(4-methyl­phen­yl)-5,6-diphenyl-2,3-dihydro­pyrazine Thiruvalluvar, A. Anuradha, N. Chitra, S. Devanathan, D. Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(24)H(22)N(2), four atoms (N—C—C—N) of the heterocyclic ring, with their attached H atoms, and all atoms of the methyl group, are disordered over two positions; the site-occupancy factor of the major component is 0.713 (6). The major disorder component of the heterocyclic ring adopts a half-chair conformation, with all substituents equatorial. The benzene ring adjacent to the methyl group forms dihedral angles of 79.68 (11) and 80.92 (11)° with the phenyl rings; the dihedral angle between adjacent phenyl rings is 59.10 (11)°. The crystal structure features three C—H⋯π inter­actions. International Union of Crystallography 2012-10-06 /pmc/articles/PMC3515189/ /pubmed/23284416 http://dx.doi.org/10.1107/S1600536812041438 Text en © Thiruvalluvar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thiruvalluvar, A.
Anuradha, N.
Chitra, S.
Devanathan, D.
Butcher, R. J.
2-Methyl-3-(4-methyl­phen­yl)-5,6-diphenyl-2,3-dihydro­pyrazine
title 2-Methyl-3-(4-methyl­phen­yl)-5,6-diphenyl-2,3-dihydro­pyrazine
title_full 2-Methyl-3-(4-methyl­phen­yl)-5,6-diphenyl-2,3-dihydro­pyrazine
title_fullStr 2-Methyl-3-(4-methyl­phen­yl)-5,6-diphenyl-2,3-dihydro­pyrazine
title_full_unstemmed 2-Methyl-3-(4-methyl­phen­yl)-5,6-diphenyl-2,3-dihydro­pyrazine
title_short 2-Methyl-3-(4-methyl­phen­yl)-5,6-diphenyl-2,3-dihydro­pyrazine
title_sort 2-methyl-3-(4-methyl­phen­yl)-5,6-diphenyl-2,3-dihydro­pyrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515189/
https://www.ncbi.nlm.nih.gov/pubmed/23284416
http://dx.doi.org/10.1107/S1600536812041438
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