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3-[Bis(dimethylamino)methylene]-1,1-diphenylurea
In the title compound, C(18)H(22)N(4)O, the C=N and C—N bond lengths in the CN(3) unit are 1.3179 (11), 1.3551 (11) and 1.3737 (11) Å, indicating double- and single-bond character, respectively. The N—C—N angles are 115.91 (8), 118.20 (8) and 125.69 (8), showing a deviation of the CN(3) plane from a...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515190/ https://www.ncbi.nlm.nih.gov/pubmed/23284417 http://dx.doi.org/10.1107/S160053681204127X |
Sumario: | In the title compound, C(18)H(22)N(4)O, the C=N and C—N bond lengths in the CN(3) unit are 1.3179 (11), 1.3551 (11) and 1.3737 (11) Å, indicating double- and single-bond character, respectively. The N—C—N angles are 115.91 (8), 118.20 (8) and 125.69 (8), showing a deviation of the CN(3) plane from an ideal trigonal–planar geometry. The bonds between the N atoms and the terminal C-methyl groups all have values close to a typical single bond [1.4529 (12)–1.4624 (12) Å]. The dihedral angle between the phenyl rings is 79.63 (4)°. In the crystal, the molecules are connected via weak C—H⋯O hydrogen bonds, generating chains along [100]. |
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