Bicyclo­[2.2.1]hept-7-yl p-bromo­benzoate

The title compound, C(14)H(15)BrO(2), contains a sterically unencumbered norbornyl group. The dihedral angle between the plane of the carboxyl­ate group and the mean plane of the adjacent benzene ring is 5.3 (2)°. The dihedral angle between the plane of the carboxyl­ate group and the norbornyl metha...

Descripción completa

Detalles Bibliográficos
Autores principales: Lloyd, Barry A., Arif, Atta M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515191/
https://www.ncbi.nlm.nih.gov/pubmed/23284418
http://dx.doi.org/10.1107/S1600536812041268
Descripción
Sumario:The title compound, C(14)H(15)BrO(2), contains a sterically unencumbered norbornyl group. The dihedral angle between the plane of the carboxyl­ate group and the mean plane of the adjacent benzene ring is 5.3 (2)°. The dihedral angle between the plane of the carboxyl­ate group and the norbornyl methano C—O bond is 4.5 (1)°, the methano C atom deviating by 0.141 (2) Å from this plane. In the crystal, mol­ecules pack as pairs of enanti­omers, with a distance of 3.747 (1) Å between the centroids of nearest parallel benzene rings.

Ejemplares similares