Bicyclo­[2.2.1]hept-7-yl p-bromo­benzoate

The title compound, C(14)H(15)BrO(2), contains a sterically unencumbered norbornyl group. The dihedral angle between the plane of the carboxyl­ate group and the mean plane of the adjacent benzene ring is 5.3 (2)°. The dihedral angle between the plane of the carboxyl­ate group and the norbornyl metha...

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Detalles Bibliográficos
Autores principales: Lloyd, Barry A., Arif, Atta M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515191/
https://www.ncbi.nlm.nih.gov/pubmed/23284418
http://dx.doi.org/10.1107/S1600536812041268
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author Lloyd, Barry A.
Arif, Atta M.
author_facet Lloyd, Barry A.
Arif, Atta M.
author_sort Lloyd, Barry A.
collection PubMed
description The title compound, C(14)H(15)BrO(2), contains a sterically unencumbered norbornyl group. The dihedral angle between the plane of the carboxyl­ate group and the mean plane of the adjacent benzene ring is 5.3 (2)°. The dihedral angle between the plane of the carboxyl­ate group and the norbornyl methano C—O bond is 4.5 (1)°, the methano C atom deviating by 0.141 (2) Å from this plane. In the crystal, mol­ecules pack as pairs of enanti­omers, with a distance of 3.747 (1) Å between the centroids of nearest parallel benzene rings.
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spelling pubmed-35151912013-01-02 Bicyclo­[2.2.1]hept-7-yl p-bromo­benzoate Lloyd, Barry A. Arif, Atta M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(15)BrO(2), contains a sterically unencumbered norbornyl group. The dihedral angle between the plane of the carboxyl­ate group and the mean plane of the adjacent benzene ring is 5.3 (2)°. The dihedral angle between the plane of the carboxyl­ate group and the norbornyl methano C—O bond is 4.5 (1)°, the methano C atom deviating by 0.141 (2) Å from this plane. In the crystal, mol­ecules pack as pairs of enanti­omers, with a distance of 3.747 (1) Å between the centroids of nearest parallel benzene rings. International Union of Crystallography 2012-10-06 /pmc/articles/PMC3515191/ /pubmed/23284418 http://dx.doi.org/10.1107/S1600536812041268 Text en © Lloyd and Arif 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lloyd, Barry A.
Arif, Atta M.
Bicyclo­[2.2.1]hept-7-yl p-bromo­benzoate
title Bicyclo­[2.2.1]hept-7-yl p-bromo­benzoate
title_full Bicyclo­[2.2.1]hept-7-yl p-bromo­benzoate
title_fullStr Bicyclo­[2.2.1]hept-7-yl p-bromo­benzoate
title_full_unstemmed Bicyclo­[2.2.1]hept-7-yl p-bromo­benzoate
title_short Bicyclo­[2.2.1]hept-7-yl p-bromo­benzoate
title_sort bicyclo­[2.2.1]hept-7-yl p-bromo­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515191/
https://www.ncbi.nlm.nih.gov/pubmed/23284418
http://dx.doi.org/10.1107/S1600536812041268
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AT arifattam bicyclo221hept7ylpbromobenzoate

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