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3,6-Dibromophenanthrene
The phenanthrene ring in the title compound, C(14)H(8)Br(2), is approximately planar [maximum deviation = 0.039 (3) Å]. In contrast, the two bromo atoms are displaced slightly from the phenanthrene plane [maximum deviation = 0.1637 (3) Å]. In the crystal, the molecules adopt a herringbone-like arra...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515201/ https://www.ncbi.nlm.nih.gov/pubmed/23284428 http://dx.doi.org/10.1107/S1600536812041621 |
Sumario: | The phenanthrene ring in the title compound, C(14)H(8)Br(2), is approximately planar [maximum deviation = 0.039 (3) Å]. In contrast, the two bromo atoms are displaced slightly from the phenanthrene plane [maximum deviation = 0.1637 (3) Å]. In the crystal, the molecules adopt a herringbone-like arrangement and form face-to-face slipped π–π stacking interactions along the b axis, with an interplanar distance of 3.544 (3) Å and slippage of 1.81 Å. The crystal studied was a racemic twin with a minor twin fraction of 0.390 (10). |
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