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3,6-Dibromo­phenanthrene

The phenanthrene ring in the title compound, C(14)H(8)Br(2), is approximately planar [maximum deviation = 0.039 (3) Å]. In contrast, the two bromo atoms are displaced slightly from the phenanthrene plane [maximum deviation = 0.1637 (3) Å]. In the crystal, the mol­ecules adopt a herringbone-like arra...

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Detalles Bibliográficos
Autores principales: Yokota, Ruri, Kitamura, Chitoshi, Kawase, Takeshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515201/
https://www.ncbi.nlm.nih.gov/pubmed/23284428
http://dx.doi.org/10.1107/S1600536812041621
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author Yokota, Ruri
Kitamura, Chitoshi
Kawase, Takeshi
author_facet Yokota, Ruri
Kitamura, Chitoshi
Kawase, Takeshi
author_sort Yokota, Ruri
collection PubMed
description The phenanthrene ring in the title compound, C(14)H(8)Br(2), is approximately planar [maximum deviation = 0.039 (3) Å]. In contrast, the two bromo atoms are displaced slightly from the phenanthrene plane [maximum deviation = 0.1637 (3) Å]. In the crystal, the mol­ecules adopt a herringbone-like arrangement and form face-to-face slipped π–π stacking inter­actions along the b axis, with an inter­planar distance of 3.544 (3) Å and slippage of 1.81 Å. The crystal studied was a racemic twin with a minor twin fraction of 0.390 (10).
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spelling pubmed-35152012013-01-02 3,6-Dibromo­phenanthrene Yokota, Ruri Kitamura, Chitoshi Kawase, Takeshi Acta Crystallogr Sect E Struct Rep Online Organic Papers The phenanthrene ring in the title compound, C(14)H(8)Br(2), is approximately planar [maximum deviation = 0.039 (3) Å]. In contrast, the two bromo atoms are displaced slightly from the phenanthrene plane [maximum deviation = 0.1637 (3) Å]. In the crystal, the mol­ecules adopt a herringbone-like arrangement and form face-to-face slipped π–π stacking inter­actions along the b axis, with an inter­planar distance of 3.544 (3) Å and slippage of 1.81 Å. The crystal studied was a racemic twin with a minor twin fraction of 0.390 (10). International Union of Crystallography 2012-10-10 /pmc/articles/PMC3515201/ /pubmed/23284428 http://dx.doi.org/10.1107/S1600536812041621 Text en © Yokota et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yokota, Ruri
Kitamura, Chitoshi
Kawase, Takeshi
3,6-Dibromo­phenanthrene
title 3,6-Dibromo­phenanthrene
title_full 3,6-Dibromo­phenanthrene
title_fullStr 3,6-Dibromo­phenanthrene
title_full_unstemmed 3,6-Dibromo­phenanthrene
title_short 3,6-Dibromo­phenanthrene
title_sort 3,6-dibromo­phenanthrene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515201/
https://www.ncbi.nlm.nih.gov/pubmed/23284428
http://dx.doi.org/10.1107/S1600536812041621
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