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3,6-Dibromophenanthrene
The phenanthrene ring in the title compound, C(14)H(8)Br(2), is approximately planar [maximum deviation = 0.039 (3) Å]. In contrast, the two bromo atoms are displaced slightly from the phenanthrene plane [maximum deviation = 0.1637 (3) Å]. In the crystal, the molecules adopt a herringbone-like arra...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515201/ https://www.ncbi.nlm.nih.gov/pubmed/23284428 http://dx.doi.org/10.1107/S1600536812041621 |
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author | Yokota, Ruri Kitamura, Chitoshi Kawase, Takeshi |
author_facet | Yokota, Ruri Kitamura, Chitoshi Kawase, Takeshi |
author_sort | Yokota, Ruri |
collection | PubMed |
description | The phenanthrene ring in the title compound, C(14)H(8)Br(2), is approximately planar [maximum deviation = 0.039 (3) Å]. In contrast, the two bromo atoms are displaced slightly from the phenanthrene plane [maximum deviation = 0.1637 (3) Å]. In the crystal, the molecules adopt a herringbone-like arrangement and form face-to-face slipped π–π stacking interactions along the b axis, with an interplanar distance of 3.544 (3) Å and slippage of 1.81 Å. The crystal studied was a racemic twin with a minor twin fraction of 0.390 (10). |
format | Online Article Text |
id | pubmed-3515201 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35152012013-01-02 3,6-Dibromophenanthrene Yokota, Ruri Kitamura, Chitoshi Kawase, Takeshi Acta Crystallogr Sect E Struct Rep Online Organic Papers The phenanthrene ring in the title compound, C(14)H(8)Br(2), is approximately planar [maximum deviation = 0.039 (3) Å]. In contrast, the two bromo atoms are displaced slightly from the phenanthrene plane [maximum deviation = 0.1637 (3) Å]. In the crystal, the molecules adopt a herringbone-like arrangement and form face-to-face slipped π–π stacking interactions along the b axis, with an interplanar distance of 3.544 (3) Å and slippage of 1.81 Å. The crystal studied was a racemic twin with a minor twin fraction of 0.390 (10). International Union of Crystallography 2012-10-10 /pmc/articles/PMC3515201/ /pubmed/23284428 http://dx.doi.org/10.1107/S1600536812041621 Text en © Yokota et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Yokota, Ruri Kitamura, Chitoshi Kawase, Takeshi 3,6-Dibromophenanthrene |
title | 3,6-Dibromophenanthrene |
title_full | 3,6-Dibromophenanthrene |
title_fullStr | 3,6-Dibromophenanthrene |
title_full_unstemmed | 3,6-Dibromophenanthrene |
title_short | 3,6-Dibromophenanthrene |
title_sort | 3,6-dibromophenanthrene |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515201/ https://www.ncbi.nlm.nih.gov/pubmed/23284428 http://dx.doi.org/10.1107/S1600536812041621 |
work_keys_str_mv | AT yokotaruri 36dibromophenanthrene AT kitamurachitoshi 36dibromophenanthrene AT kawasetakeshi 36dibromophenanthrene |