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2-(4-Meth­oxy­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole

The asymmetric unit of the title compound, C(25)H(22)N(2)O, contains two independent mol­ecules (A and B), with significantly different conformations. In mol­ecule A, the central imidazole ring makes dihedral angles of 88.26 (10) and 12.74 (11)° with the two phenyl rings, and 22.06 (9)° with the ben...

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Autores principales: Akkurt, Mehmet, Marzouk, Adel A., Abbasov, Vagif. M., Abdelhamid, Antar A., Gurbanov, Atash V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515219/
https://www.ncbi.nlm.nih.gov/pubmed/23284439
http://dx.doi.org/10.1107/S1600536812041979
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author Akkurt, Mehmet
Marzouk, Adel A.
Abbasov, Vagif. M.
Abdelhamid, Antar A.
Gurbanov, Atash V.
author_facet Akkurt, Mehmet
Marzouk, Adel A.
Abbasov, Vagif. M.
Abdelhamid, Antar A.
Gurbanov, Atash V.
author_sort Akkurt, Mehmet
collection PubMed
description The asymmetric unit of the title compound, C(25)H(22)N(2)O, contains two independent mol­ecules (A and B), with significantly different conformations. In mol­ecule A, the central imidazole ring makes dihedral angles of 88.26 (10) and 12.74 (11)° with the two phenyl rings, and 22.06 (9)° with the benzene ring. In mol­ecule B, one of the phenyl rings is disordered over two sites, each having an occupancy of 0.5. Here the central imidazole ring forms dihedral angles of 79.24 (10)° with the ordered phenyl ring, and 3.5 (5) and 22.6 (5)° with the two parts of the disordered phenyl ring. The dihedral angle involving the benzene ring is 67.49 (10)°. The —N—C(H(2))—C(H)—C(H(2)) torsion angles of the prop-1-ene group in the two mol­ecules are very similar, 0.5 (3) and 1.3 (4)° for mol­ecules A and B, respectively. The crystal structure is stabilized by C—H⋯π inter­actions.
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spelling pubmed-35152192013-01-02 2-(4-Meth­oxy­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole Akkurt, Mehmet Marzouk, Adel A. Abbasov, Vagif. M. Abdelhamid, Antar A. Gurbanov, Atash V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(25)H(22)N(2)O, contains two independent mol­ecules (A and B), with significantly different conformations. In mol­ecule A, the central imidazole ring makes dihedral angles of 88.26 (10) and 12.74 (11)° with the two phenyl rings, and 22.06 (9)° with the benzene ring. In mol­ecule B, one of the phenyl rings is disordered over two sites, each having an occupancy of 0.5. Here the central imidazole ring forms dihedral angles of 79.24 (10)° with the ordered phenyl ring, and 3.5 (5) and 22.6 (5)° with the two parts of the disordered phenyl ring. The dihedral angle involving the benzene ring is 67.49 (10)°. The —N—C(H(2))—C(H)—C(H(2)) torsion angles of the prop-1-ene group in the two mol­ecules are very similar, 0.5 (3) and 1.3 (4)° for mol­ecules A and B, respectively. The crystal structure is stabilized by C—H⋯π inter­actions. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515219/ /pubmed/23284439 http://dx.doi.org/10.1107/S1600536812041979 Text en © Akkurt et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Marzouk, Adel A.
Abbasov, Vagif. M.
Abdelhamid, Antar A.
Gurbanov, Atash V.
2-(4-Meth­oxy­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole
title 2-(4-Meth­oxy­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole
title_full 2-(4-Meth­oxy­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole
title_fullStr 2-(4-Meth­oxy­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole
title_full_unstemmed 2-(4-Meth­oxy­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole
title_short 2-(4-Meth­oxy­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole
title_sort 2-(4-meth­oxy­phen­yl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1h-imidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515219/
https://www.ncbi.nlm.nih.gov/pubmed/23284439
http://dx.doi.org/10.1107/S1600536812041979
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