Cargando…
2-(4-Methoxyphenyl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole
The asymmetric unit of the title compound, C(25)H(22)N(2)O, contains two independent molecules (A and B), with significantly different conformations. In molecule A, the central imidazole ring makes dihedral angles of 88.26 (10) and 12.74 (11)° with the two phenyl rings, and 22.06 (9)° with the ben...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515219/ https://www.ncbi.nlm.nih.gov/pubmed/23284439 http://dx.doi.org/10.1107/S1600536812041979 |
_version_ | 1782252136500822016 |
---|---|
author | Akkurt, Mehmet Marzouk, Adel A. Abbasov, Vagif. M. Abdelhamid, Antar A. Gurbanov, Atash V. |
author_facet | Akkurt, Mehmet Marzouk, Adel A. Abbasov, Vagif. M. Abdelhamid, Antar A. Gurbanov, Atash V. |
author_sort | Akkurt, Mehmet |
collection | PubMed |
description | The asymmetric unit of the title compound, C(25)H(22)N(2)O, contains two independent molecules (A and B), with significantly different conformations. In molecule A, the central imidazole ring makes dihedral angles of 88.26 (10) and 12.74 (11)° with the two phenyl rings, and 22.06 (9)° with the benzene ring. In molecule B, one of the phenyl rings is disordered over two sites, each having an occupancy of 0.5. Here the central imidazole ring forms dihedral angles of 79.24 (10)° with the ordered phenyl ring, and 3.5 (5) and 22.6 (5)° with the two parts of the disordered phenyl ring. The dihedral angle involving the benzene ring is 67.49 (10)°. The —N—C(H(2))—C(H)—C(H(2)) torsion angles of the prop-1-ene group in the two molecules are very similar, 0.5 (3) and 1.3 (4)° for molecules A and B, respectively. The crystal structure is stabilized by C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3515219 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35152192013-01-02 2-(4-Methoxyphenyl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole Akkurt, Mehmet Marzouk, Adel A. Abbasov, Vagif. M. Abdelhamid, Antar A. Gurbanov, Atash V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(25)H(22)N(2)O, contains two independent molecules (A and B), with significantly different conformations. In molecule A, the central imidazole ring makes dihedral angles of 88.26 (10) and 12.74 (11)° with the two phenyl rings, and 22.06 (9)° with the benzene ring. In molecule B, one of the phenyl rings is disordered over two sites, each having an occupancy of 0.5. Here the central imidazole ring forms dihedral angles of 79.24 (10)° with the ordered phenyl ring, and 3.5 (5) and 22.6 (5)° with the two parts of the disordered phenyl ring. The dihedral angle involving the benzene ring is 67.49 (10)°. The —N—C(H(2))—C(H)—C(H(2)) torsion angles of the prop-1-ene group in the two molecules are very similar, 0.5 (3) and 1.3 (4)° for molecules A and B, respectively. The crystal structure is stabilized by C—H⋯π interactions. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515219/ /pubmed/23284439 http://dx.doi.org/10.1107/S1600536812041979 Text en © Akkurt et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Akkurt, Mehmet Marzouk, Adel A. Abbasov, Vagif. M. Abdelhamid, Antar A. Gurbanov, Atash V. 2-(4-Methoxyphenyl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole |
title | 2-(4-Methoxyphenyl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole |
title_full | 2-(4-Methoxyphenyl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole |
title_fullStr | 2-(4-Methoxyphenyl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole |
title_full_unstemmed | 2-(4-Methoxyphenyl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole |
title_short | 2-(4-Methoxyphenyl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1H-imidazole |
title_sort | 2-(4-methoxyphenyl)-4,5-diphenyl-1-(prop-2-en-1-yl)-1h-imidazole |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515219/ https://www.ncbi.nlm.nih.gov/pubmed/23284439 http://dx.doi.org/10.1107/S1600536812041979 |
work_keys_str_mv | AT akkurtmehmet 24methoxyphenyl45diphenyl1prop2en1yl1himidazole AT marzoukadela 24methoxyphenyl45diphenyl1prop2en1yl1himidazole AT abbasovvagifm 24methoxyphenyl45diphenyl1prop2en1yl1himidazole AT abdelhamidantara 24methoxyphenyl45diphenyl1prop2en1yl1himidazole AT gurbanovatashv 24methoxyphenyl45diphenyl1prop2en1yl1himidazole |