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4-Morpholinecarboxamidine
In the crystal structure of the title compound, C(5)H(11)N(3)O, the C=N and C—N bond lengths in the CN(3) unit are 1.2971 (14), 1.3595 (14) (NH(2)) and 1.3902 (13) Å, indicating double- and single-bond character, respectively. The N—C—N angles are 115.49 (9)°, 119.68 (10)° and 124.83 (10)°, showing...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515223/ https://www.ncbi.nlm.nih.gov/pubmed/23284443 http://dx.doi.org/10.1107/S1600536812042201 |
| _version_ | 1782252137436151808 |
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| author | Tiritiris, Ioannis |
| author_facet | Tiritiris, Ioannis |
| author_sort | Tiritiris, Ioannis |
| collection | PubMed |
| description | In the crystal structure of the title compound, C(5)H(11)N(3)O, the C=N and C—N bond lengths in the CN(3) unit are 1.2971 (14), 1.3595 (14) (NH(2)) and 1.3902 (13) Å, indicating double- and single-bond character, respectively. The N—C—N angles are 115.49 (9)°, 119.68 (10)° and 124.83 (10)°, showing a deviation of the CN(3) plane from an ideal trigonal–planar geometry. The morpholine ring is in a chair conformation. In the crystal, the molecules are linked by N—H⋯N and N—H⋯O hydrogen bonds, generating a three-dimensional network. |
| format | Online Article Text |
| id | pubmed-3515223 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35152232013-01-02 4-Morpholinecarboxamidine Tiritiris, Ioannis Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(5)H(11)N(3)O, the C=N and C—N bond lengths in the CN(3) unit are 1.2971 (14), 1.3595 (14) (NH(2)) and 1.3902 (13) Å, indicating double- and single-bond character, respectively. The N—C—N angles are 115.49 (9)°, 119.68 (10)° and 124.83 (10)°, showing a deviation of the CN(3) plane from an ideal trigonal–planar geometry. The morpholine ring is in a chair conformation. In the crystal, the molecules are linked by N—H⋯N and N—H⋯O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515223/ /pubmed/23284443 http://dx.doi.org/10.1107/S1600536812042201 Text en © Ioannis Tiritiris 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Tiritiris, Ioannis 4-Morpholinecarboxamidine |
| title | 4-Morpholinecarboxamidine |
| title_full | 4-Morpholinecarboxamidine |
| title_fullStr | 4-Morpholinecarboxamidine |
| title_full_unstemmed | 4-Morpholinecarboxamidine |
| title_short | 4-Morpholinecarboxamidine |
| title_sort | 4-morpholinecarboxamidine |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515223/ https://www.ncbi.nlm.nih.gov/pubmed/23284443 http://dx.doi.org/10.1107/S1600536812042201 |
| work_keys_str_mv | AT tiritirisioannis 4morpholinecarboxamidine |