Methyl (2E)-2-cyano-3-(dimethyl­amino)­prop-2-enoate

In the title compound, C(7)H(10)N(2)O(2), the dimethyl­amino group is twisted slightly relative to the acrylate fragment, forming a dihedral angle of 11.6 (1)°. In the crystal, molecules are linked via pairs of bifurcated C—H/H⋯O hydrogen bonds, forming inversion dimers, which are further connected...

Descripción completa

Detalles Bibliográficos
Autores principales: Kant, Rajni, Gupta, Vivek K., Kapoor, Kamini, Patil, D. R., Salunkhe, D. K., Deshmukh, Madhukar B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515226/
https://www.ncbi.nlm.nih.gov/pubmed/23284446
http://dx.doi.org/10.1107/S1600536812042304
_version_ 1782252138128211968
author Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Patil, D. R.
Salunkhe, D. K.
Deshmukh, Madhukar B.
author_facet Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Patil, D. R.
Salunkhe, D. K.
Deshmukh, Madhukar B.
author_sort Kant, Rajni
collection PubMed
description In the title compound, C(7)H(10)N(2)O(2), the dimethyl­amino group is twisted slightly relative to the acrylate fragment, forming a dihedral angle of 11.6 (1)°. In the crystal, molecules are linked via pairs of bifurcated C—H/H⋯O hydrogen bonds, forming inversion dimers, which are further connected by C—H⋯N hydrogen bonds into chains along the a-axis direction.
format Online
Article
Text
id pubmed-3515226
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-35152262013-01-02 Methyl (2E)-2-cyano-3-(dimethyl­amino)­prop-2-enoate Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Patil, D. R. Salunkhe, D. K. Deshmukh, Madhukar B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(10)N(2)O(2), the dimethyl­amino group is twisted slightly relative to the acrylate fragment, forming a dihedral angle of 11.6 (1)°. In the crystal, molecules are linked via pairs of bifurcated C—H/H⋯O hydrogen bonds, forming inversion dimers, which are further connected by C—H⋯N hydrogen bonds into chains along the a-axis direction. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515226/ /pubmed/23284446 http://dx.doi.org/10.1107/S1600536812042304 Text en © Kant et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Patil, D. R.
Salunkhe, D. K.
Deshmukh, Madhukar B.
Methyl (2E)-2-cyano-3-(dimethyl­amino)­prop-2-enoate
title Methyl (2E)-2-cyano-3-(dimethyl­amino)­prop-2-enoate
title_full Methyl (2E)-2-cyano-3-(dimethyl­amino)­prop-2-enoate
title_fullStr Methyl (2E)-2-cyano-3-(dimethyl­amino)­prop-2-enoate
title_full_unstemmed Methyl (2E)-2-cyano-3-(dimethyl­amino)­prop-2-enoate
title_short Methyl (2E)-2-cyano-3-(dimethyl­amino)­prop-2-enoate
title_sort methyl (2e)-2-cyano-3-(dimethyl­amino)­prop-2-enoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515226/
https://www.ncbi.nlm.nih.gov/pubmed/23284446
http://dx.doi.org/10.1107/S1600536812042304
work_keys_str_mv AT kantrajni methyl2e2cyano3dimethylaminoprop2enoate
AT guptavivekk methyl2e2cyano3dimethylaminoprop2enoate
AT kapoorkamini methyl2e2cyano3dimethylaminoprop2enoate
AT patildr methyl2e2cyano3dimethylaminoprop2enoate
AT salunkhedk methyl2e2cyano3dimethylaminoprop2enoate
AT deshmukhmadhukarb methyl2e2cyano3dimethylaminoprop2enoate

Ejemplares similares