2,2′-Diiodo­azobenzene

The mol­ecular structure of the title compound, C(12)H(8)I(2)N(2) [systematic name: (E)-bis­(2-iodo­phen­yl)diazene], exhibits an essentially planar trans geometry [maximum deviation = 0.022 (4) Å] with the iodine atoms ortho to the azo bridge. In the crystal, offset π-stacking leads to the formatio...

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Detalles Bibliográficos
Autores principales: Elder, Philip J. W., Vargas-Baca, Ignacio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515232/
https://www.ncbi.nlm.nih.gov/pubmed/23284452
http://dx.doi.org/10.1107/S1600536812040718
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author Elder, Philip J. W.
Vargas-Baca, Ignacio
author_facet Elder, Philip J. W.
Vargas-Baca, Ignacio
author_sort Elder, Philip J. W.
collection PubMed
description The mol­ecular structure of the title compound, C(12)H(8)I(2)N(2) [systematic name: (E)-bis­(2-iodo­phen­yl)diazene], exhibits an essentially planar trans geometry [maximum deviation = 0.022 (4) Å] with the iodine atoms ortho to the azo bridge. In the crystal, offset π-stacking leads to the formation of columns along the a axis [closest C⋯C distance = 3.383 (4) Å].
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spelling pubmed-35152322013-01-02 2,2′-Diiodo­azobenzene Elder, Philip J. W. Vargas-Baca, Ignacio Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular structure of the title compound, C(12)H(8)I(2)N(2) [systematic name: (E)-bis­(2-iodo­phen­yl)diazene], exhibits an essentially planar trans geometry [maximum deviation = 0.022 (4) Å] with the iodine atoms ortho to the azo bridge. In the crystal, offset π-stacking leads to the formation of columns along the a axis [closest C⋯C distance = 3.383 (4) Å]. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515232/ /pubmed/23284452 http://dx.doi.org/10.1107/S1600536812040718 Text en © Elder and Vargas-Baca 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Elder, Philip J. W.
Vargas-Baca, Ignacio
2,2′-Diiodo­azobenzene
title 2,2′-Diiodo­azobenzene
title_full 2,2′-Diiodo­azobenzene
title_fullStr 2,2′-Diiodo­azobenzene
title_full_unstemmed 2,2′-Diiodo­azobenzene
title_short 2,2′-Diiodo­azobenzene
title_sort 2,2′-diiodo­azobenzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515232/
https://www.ncbi.nlm.nih.gov/pubmed/23284452
http://dx.doi.org/10.1107/S1600536812040718
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