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5-(1-Benzyl-1H-1,2,3-triazol-4-yl)-2,1,3-benzoxadiazole
In the title compound, C(15)H(11)N(5)O, which was prepared as part of a study to identify fluorogenic substrates for the Cu-catalysed azide–alkyne cycloaddition (CuAAC) reaction, the benzoxadiazole unit and the triazole ring are much more closely coplanar [dihedral angle = 10.92 (7)°] than either...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515234/ https://www.ncbi.nlm.nih.gov/pubmed/23284454 http://dx.doi.org/10.1107/S1600536812041827 |
Sumario: | In the title compound, C(15)H(11)N(5)O, which was prepared as part of a study to identify fluorogenic substrates for the Cu-catalysed azide–alkyne cycloaddition (CuAAC) reaction, the benzoxadiazole unit and the triazole ring are much more closely coplanar [dihedral angle = 10.92 (7)°] than either is to the benzyl group [dihedral angles = 69.13 (3)° and 78.20 (4)°, respectively]. The crystal structure features two different sets of weak intermolecular C—H⋯N interactions between adjacent benzoxadiazole and triazole rings, forming a chain that propagates in the [-110] direction parallel to the ab plane. |
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