Dibenzo[b,f][1,4]thia­zepin-11-yl-diethyl-amine

In the title compound, C(17)H(18)N(2)S, the thia­zepine ring adopts a boat conformation and the dihedral angle between the benzene rings is 75.92 (5)°, resulting in a butterfly-like conformation. In the crystal, mol­ecules are connected via weak C(aromatic)—H⋯N contacts involving the imine N atom as...

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Detalles Bibliográficos
Autores principales: Altamura, Maria, Guidi, Antonio, Jierry, Loic, Paoli, Paola, Rossi, Patrizia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515236/
https://www.ncbi.nlm.nih.gov/pubmed/23284456
http://dx.doi.org/10.1107/S1600536812042328
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author Altamura, Maria
Guidi, Antonio
Jierry, Loic
Paoli, Paola
Rossi, Patrizia
author_facet Altamura, Maria
Guidi, Antonio
Jierry, Loic
Paoli, Paola
Rossi, Patrizia
author_sort Altamura, Maria
collection PubMed
description In the title compound, C(17)H(18)N(2)S, the thia­zepine ring adopts a boat conformation and the dihedral angle between the benzene rings is 75.92 (5)°, resulting in a butterfly-like conformation. In the crystal, mol­ecules are connected via weak C(aromatic)—H⋯N contacts involving the imine N atom as acceptor and through a quite short C—H⋯π inter­action. The resulting mol­ecular chains propagate along the c-axis direction.
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spelling pubmed-35152362013-01-02 Dibenzo[b,f][1,4]thia­zepin-11-yl-diethyl-amine Altamura, Maria Guidi, Antonio Jierry, Loic Paoli, Paola Rossi, Patrizia Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(18)N(2)S, the thia­zepine ring adopts a boat conformation and the dihedral angle between the benzene rings is 75.92 (5)°, resulting in a butterfly-like conformation. In the crystal, mol­ecules are connected via weak C(aromatic)—H⋯N contacts involving the imine N atom as acceptor and through a quite short C—H⋯π inter­action. The resulting mol­ecular chains propagate along the c-axis direction. International Union of Crystallography 2012-10-13 /pmc/articles/PMC3515236/ /pubmed/23284456 http://dx.doi.org/10.1107/S1600536812042328 Text en © Altamura et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Altamura, Maria
Guidi, Antonio
Jierry, Loic
Paoli, Paola
Rossi, Patrizia
Dibenzo[b,f][1,4]thia­zepin-11-yl-diethyl-amine
title Dibenzo[b,f][1,4]thia­zepin-11-yl-diethyl-amine
title_full Dibenzo[b,f][1,4]thia­zepin-11-yl-diethyl-amine
title_fullStr Dibenzo[b,f][1,4]thia­zepin-11-yl-diethyl-amine
title_full_unstemmed Dibenzo[b,f][1,4]thia­zepin-11-yl-diethyl-amine
title_short Dibenzo[b,f][1,4]thia­zepin-11-yl-diethyl-amine
title_sort dibenzo[b,f][1,4]thia­zepin-11-yl-diethyl-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515236/
https://www.ncbi.nlm.nih.gov/pubmed/23284456
http://dx.doi.org/10.1107/S1600536812042328
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AT guidiantonio dibenzobf14thiazepin11yldiethylamine
AT jierryloic dibenzobf14thiazepin11yldiethylamine
AT paolipaola dibenzobf14thiazepin11yldiethylamine
AT rossipatrizia dibenzobf14thiazepin11yldiethylamine

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