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2-(1H-Indol-3-yl)acetohydrazide

In the title compound C(10)H(11)N(3)O, the mean plane of the indole ring system (r.m.s. deviation 0.0131 Å) subtends a dihedral angle of 87.27 (5)° to the almost planar acetohydrazide substituent (r.m.s. deviation 0.0291 Å). In the crystal, bifurcated N—H⋯(O,N) and N—H⋯N hydrogen bonds involving the...

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Autores principales: Sidra, Lala Rukh, Khan, Islam Ullah, Yar, Muhammad, Simpson, Jim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515242/
https://www.ncbi.nlm.nih.gov/pubmed/23284462
http://dx.doi.org/10.1107/S1600536812041694
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author Sidra, Lala Rukh
Khan, Islam Ullah
Yar, Muhammad
Simpson, Jim
author_facet Sidra, Lala Rukh
Khan, Islam Ullah
Yar, Muhammad
Simpson, Jim
author_sort Sidra, Lala Rukh
collection PubMed
description In the title compound C(10)H(11)N(3)O, the mean plane of the indole ring system (r.m.s. deviation 0.0131 Å) subtends a dihedral angle of 87.27 (5)° to the almost planar acetohydrazide substituent (r.m.s. deviation 0.0291 Å). In the crystal, bifurcated N—H⋯(O,N) and N—H⋯N hydrogen bonds involving the pyrrole N–H grouping combine to form zigzag chains along a. Additional N—H⋯O contacts from the hydrazide N–H group augmented by C—H⋯π inter­actions link the mol­ecules into chains along the a axis. The overall effect of these contacts is a three-dimensional network structure with mol­ecules stacked along the b-axis direction.
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spelling pubmed-35152422013-01-02 2-(1H-Indol-3-yl)acetohydrazide Sidra, Lala Rukh Khan, Islam Ullah Yar, Muhammad Simpson, Jim Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound C(10)H(11)N(3)O, the mean plane of the indole ring system (r.m.s. deviation 0.0131 Å) subtends a dihedral angle of 87.27 (5)° to the almost planar acetohydrazide substituent (r.m.s. deviation 0.0291 Å). In the crystal, bifurcated N—H⋯(O,N) and N—H⋯N hydrogen bonds involving the pyrrole N–H grouping combine to form zigzag chains along a. Additional N—H⋯O contacts from the hydrazide N–H group augmented by C—H⋯π inter­actions link the mol­ecules into chains along the a axis. The overall effect of these contacts is a three-dimensional network structure with mol­ecules stacked along the b-axis direction. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515242/ /pubmed/23284462 http://dx.doi.org/10.1107/S1600536812041694 Text en © Sidra et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sidra, Lala Rukh
Khan, Islam Ullah
Yar, Muhammad
Simpson, Jim
2-(1H-Indol-3-yl)acetohydrazide
title 2-(1H-Indol-3-yl)acetohydrazide
title_full 2-(1H-Indol-3-yl)acetohydrazide
title_fullStr 2-(1H-Indol-3-yl)acetohydrazide
title_full_unstemmed 2-(1H-Indol-3-yl)acetohydrazide
title_short 2-(1H-Indol-3-yl)acetohydrazide
title_sort 2-(1h-indol-3-yl)acetohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515242/
https://www.ncbi.nlm.nih.gov/pubmed/23284462
http://dx.doi.org/10.1107/S1600536812041694
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