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[(E)-1-(Naph­thalen-2-yl)ethyl­idene](naph­thalen-1-ylmethyl)amine

The title compound, C(23)H(19)N, was obtained unexpectedly from the reaction of [Eu(nta)(3)(PzPy)] {Hnta = 1-(2-naphtho­yl)-3,3,3-trifluoro­acetone and PzPy = 2-[3(5)-pyrazol­yl]pyridine} with 1-naphthyl­methyl­amine. The 1- and 2-naphthyl groups are essentially planar [r.m.s. deviations of 0.007 an...

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Detalles Bibliográficos
Autores principales: Bruno, Sofia M., Fernandes, José A., Gonçalves, Isabel S., Almeida Paz, Filipe A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515244/
https://www.ncbi.nlm.nih.gov/pubmed/23284464
http://dx.doi.org/10.1107/S1600536812041414
Descripción
Sumario:The title compound, C(23)H(19)N, was obtained unexpectedly from the reaction of [Eu(nta)(3)(PzPy)] {Hnta = 1-(2-naphtho­yl)-3,3,3-trifluoro­acetone and PzPy = 2-[3(5)-pyrazol­yl]pyridine} with 1-naphthyl­methyl­amine. The 1- and 2-naphthyl groups are essentially planar [r.m.s. deviations of 0.007 and 0.011 Å, respectively] and subtend angles of 38.69 (11) and 16.50 (11)°, respectively, with the central CH(3)—C=N—CH(2) unit, which is also almost planar [r.m.s. deviation = 0.002 Å]. In the crystal, the mol­ecules are disposed in zigzag-type fashion, forming layers perpendicular to [100]. Weak supra­molecular C—H⋯π inter­actions contribute to the packing forces.