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[(E)-1-(Naph­thalen-2-yl)ethyl­idene](naph­thalen-1-ylmethyl)amine

The title compound, C(23)H(19)N, was obtained unexpectedly from the reaction of [Eu(nta)(3)(PzPy)] {Hnta = 1-(2-naphtho­yl)-3,3,3-trifluoro­acetone and PzPy = 2-[3(5)-pyrazol­yl]pyridine} with 1-naphthyl­methyl­amine. The 1- and 2-naphthyl groups are essentially planar [r.m.s. deviations of 0.007 an...

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Autores principales: Bruno, Sofia M., Fernandes, José A., Gonçalves, Isabel S., Almeida Paz, Filipe A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515244/
https://www.ncbi.nlm.nih.gov/pubmed/23284464
http://dx.doi.org/10.1107/S1600536812041414
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author Bruno, Sofia M.
Fernandes, José A.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
author_facet Bruno, Sofia M.
Fernandes, José A.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
author_sort Bruno, Sofia M.
collection PubMed
description The title compound, C(23)H(19)N, was obtained unexpectedly from the reaction of [Eu(nta)(3)(PzPy)] {Hnta = 1-(2-naphtho­yl)-3,3,3-trifluoro­acetone and PzPy = 2-[3(5)-pyrazol­yl]pyridine} with 1-naphthyl­methyl­amine. The 1- and 2-naphthyl groups are essentially planar [r.m.s. deviations of 0.007 and 0.011 Å, respectively] and subtend angles of 38.69 (11) and 16.50 (11)°, respectively, with the central CH(3)—C=N—CH(2) unit, which is also almost planar [r.m.s. deviation = 0.002 Å]. In the crystal, the mol­ecules are disposed in zigzag-type fashion, forming layers perpendicular to [100]. Weak supra­molecular C—H⋯π inter­actions contribute to the packing forces.
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spelling pubmed-35152442013-01-02 [(E)-1-(Naph­thalen-2-yl)ethyl­idene](naph­thalen-1-ylmethyl)amine Bruno, Sofia M. Fernandes, José A. Gonçalves, Isabel S. Almeida Paz, Filipe A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(23)H(19)N, was obtained unexpectedly from the reaction of [Eu(nta)(3)(PzPy)] {Hnta = 1-(2-naphtho­yl)-3,3,3-trifluoro­acetone and PzPy = 2-[3(5)-pyrazol­yl]pyridine} with 1-naphthyl­methyl­amine. The 1- and 2-naphthyl groups are essentially planar [r.m.s. deviations of 0.007 and 0.011 Å, respectively] and subtend angles of 38.69 (11) and 16.50 (11)°, respectively, with the central CH(3)—C=N—CH(2) unit, which is also almost planar [r.m.s. deviation = 0.002 Å]. In the crystal, the mol­ecules are disposed in zigzag-type fashion, forming layers perpendicular to [100]. Weak supra­molecular C—H⋯π inter­actions contribute to the packing forces. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515244/ /pubmed/23284464 http://dx.doi.org/10.1107/S1600536812041414 Text en © Bruno et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bruno, Sofia M.
Fernandes, José A.
Gonçalves, Isabel S.
Almeida Paz, Filipe A.
[(E)-1-(Naph­thalen-2-yl)ethyl­idene](naph­thalen-1-ylmethyl)amine
title [(E)-1-(Naph­thalen-2-yl)ethyl­idene](naph­thalen-1-ylmethyl)amine
title_full [(E)-1-(Naph­thalen-2-yl)ethyl­idene](naph­thalen-1-ylmethyl)amine
title_fullStr [(E)-1-(Naph­thalen-2-yl)ethyl­idene](naph­thalen-1-ylmethyl)amine
title_full_unstemmed [(E)-1-(Naph­thalen-2-yl)ethyl­idene](naph­thalen-1-ylmethyl)amine
title_short [(E)-1-(Naph­thalen-2-yl)ethyl­idene](naph­thalen-1-ylmethyl)amine
title_sort [(e)-1-(naph­thalen-2-yl)ethyl­idene](naph­thalen-1-ylmethyl)amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515244/
https://www.ncbi.nlm.nih.gov/pubmed/23284464
http://dx.doi.org/10.1107/S1600536812041414
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