3-tert-Butyl 5-methyl (2R,4S,5R)-2-(4-methoxyphenyl)-4-(3-nitrophenyl)-1,3-oxazolidine-3,5-dicarboxylate

The title mol­ecule, C(23)H(26)N(2)O(8), was synthesized in three steps starting from m-nitro­cinnamic acid. The central oxazolidine ring adopts an almost perfect envelope conformation with the O atom as the flap [puckering parameter ϕ = 0.3 (6)°]. The dihedral angle formed by the benzene rings is 6...

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Detalles Bibliográficos
Autores principales: Montiel-Smith, Sara, Bernès, Sylvain, Sandoval-Ramírez, Jesús, Meza-Reyes, Socorro, Dubois, Joëlle
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515246/
https://www.ncbi.nlm.nih.gov/pubmed/23284466
http://dx.doi.org/10.1107/S160053681204192X
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author Montiel-Smith, Sara
Bernès, Sylvain
Sandoval-Ramírez, Jesús
Meza-Reyes, Socorro
Dubois, Joëlle
author_facet Montiel-Smith, Sara
Bernès, Sylvain
Sandoval-Ramírez, Jesús
Meza-Reyes, Socorro
Dubois, Joëlle
author_sort Montiel-Smith, Sara
collection PubMed
description The title mol­ecule, C(23)H(26)N(2)O(8), was synthesized in three steps starting from m-nitro­cinnamic acid. The central oxazolidine ring adopts an almost perfect envelope conformation with the O atom as the flap [puckering parameter ϕ = 0.3 (6)°]. The dihedral angle formed by the benzene rings is 61.81 (9)°. In the crystal, mol­ecules are connected into double chains parallel to [010] by C—H⋯O hydrogen bonds. The absolute configuration was assigned from the synthetic procedure.
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spelling pubmed-35152462013-01-02 3-tert-Butyl 5-methyl (2R,4S,5R)-2-(4-methoxyphenyl)-4-(3-nitrophenyl)-1,3-oxazolidine-3,5-dicarboxylate Montiel-Smith, Sara Bernès, Sylvain Sandoval-Ramírez, Jesús Meza-Reyes, Socorro Dubois, Joëlle Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(23)H(26)N(2)O(8), was synthesized in three steps starting from m-nitro­cinnamic acid. The central oxazolidine ring adopts an almost perfect envelope conformation with the O atom as the flap [puckering parameter ϕ = 0.3 (6)°]. The dihedral angle formed by the benzene rings is 61.81 (9)°. In the crystal, mol­ecules are connected into double chains parallel to [010] by C—H⋯O hydrogen bonds. The absolute configuration was assigned from the synthetic procedure. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515246/ /pubmed/23284466 http://dx.doi.org/10.1107/S160053681204192X Text en © Montiel-Smith et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Montiel-Smith, Sara
Bernès, Sylvain
Sandoval-Ramírez, Jesús
Meza-Reyes, Socorro
Dubois, Joëlle
3-tert-Butyl 5-methyl (2R,4S,5R)-2-(4-methoxyphenyl)-4-(3-nitrophenyl)-1,3-oxazolidine-3,5-dicarboxylate
title 3-tert-Butyl 5-methyl (2R,4S,5R)-2-(4-methoxyphenyl)-4-(3-nitrophenyl)-1,3-oxazolidine-3,5-dicarboxylate
title_full 3-tert-Butyl 5-methyl (2R,4S,5R)-2-(4-methoxyphenyl)-4-(3-nitrophenyl)-1,3-oxazolidine-3,5-dicarboxylate
title_fullStr 3-tert-Butyl 5-methyl (2R,4S,5R)-2-(4-methoxyphenyl)-4-(3-nitrophenyl)-1,3-oxazolidine-3,5-dicarboxylate
title_full_unstemmed 3-tert-Butyl 5-methyl (2R,4S,5R)-2-(4-methoxyphenyl)-4-(3-nitrophenyl)-1,3-oxazolidine-3,5-dicarboxylate
title_short 3-tert-Butyl 5-methyl (2R,4S,5R)-2-(4-methoxyphenyl)-4-(3-nitrophenyl)-1,3-oxazolidine-3,5-dicarboxylate
title_sort 3-tert-butyl 5-methyl (2r,4s,5r)-2-(4-methoxyphenyl)-4-(3-nitrophenyl)-1,3-oxazolidine-3,5-dicarboxylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515246/
https://www.ncbi.nlm.nih.gov/pubmed/23284466
http://dx.doi.org/10.1107/S160053681204192X
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