Tris[(6S)-6-hy­droxy-4-epi-shikimic acid] monohydrate: an enanti­omerically pure hy­droxy­lated shikimic acid derived from methyl shikimate

The title compound, 3C(7)H(10)O(6)·H(2)O, is the enanti­omerically pure product of a multi-step synthesis from the enanti­omerically pure natural shikimic acid. The asymmetric unit contains three mol­ecules of the acid and one mol­ecule of water. The cyclo­hexene rings of the acids have half-chair c...

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Autores principales: Griesbeck, Axel G., Miara, Claus, Neudörfl, Jörg-M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515248/
https://www.ncbi.nlm.nih.gov/pubmed/23284468
http://dx.doi.org/10.1107/S1600536812041256
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author Griesbeck, Axel G.
Miara, Claus
Neudörfl, Jörg-M.
author_facet Griesbeck, Axel G.
Miara, Claus
Neudörfl, Jörg-M.
author_sort Griesbeck, Axel G.
collection PubMed
description The title compound, 3C(7)H(10)O(6)·H(2)O, is the enanti­omerically pure product of a multi-step synthesis from the enanti­omerically pure natural shikimic acid. The asymmetric unit contains three mol­ecules of the acid and one mol­ecule of water. The cyclo­hexene rings of the acids have half-chair conformations. The carboxyl­ate, the four hydroxide groups and the additional water mol­ecule form a complex three-dimensional hydrogen-bonding network.
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spelling pubmed-35152482013-01-02 Tris[(6S)-6-hy­droxy-4-epi-shikimic acid] monohydrate: an enanti­omerically pure hy­droxy­lated shikimic acid derived from methyl shikimate Griesbeck, Axel G. Miara, Claus Neudörfl, Jörg-M. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, 3C(7)H(10)O(6)·H(2)O, is the enanti­omerically pure product of a multi-step synthesis from the enanti­omerically pure natural shikimic acid. The asymmetric unit contains three mol­ecules of the acid and one mol­ecule of water. The cyclo­hexene rings of the acids have half-chair conformations. The carboxyl­ate, the four hydroxide groups and the additional water mol­ecule form a complex three-dimensional hydrogen-bonding network. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515248/ /pubmed/23284468 http://dx.doi.org/10.1107/S1600536812041256 Text en © Griesbeck et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Griesbeck, Axel G.
Miara, Claus
Neudörfl, Jörg-M.
Tris[(6S)-6-hy­droxy-4-epi-shikimic acid] monohydrate: an enanti­omerically pure hy­droxy­lated shikimic acid derived from methyl shikimate
title Tris[(6S)-6-hy­droxy-4-epi-shikimic acid] monohydrate: an enanti­omerically pure hy­droxy­lated shikimic acid derived from methyl shikimate
title_full Tris[(6S)-6-hy­droxy-4-epi-shikimic acid] monohydrate: an enanti­omerically pure hy­droxy­lated shikimic acid derived from methyl shikimate
title_fullStr Tris[(6S)-6-hy­droxy-4-epi-shikimic acid] monohydrate: an enanti­omerically pure hy­droxy­lated shikimic acid derived from methyl shikimate
title_full_unstemmed Tris[(6S)-6-hy­droxy-4-epi-shikimic acid] monohydrate: an enanti­omerically pure hy­droxy­lated shikimic acid derived from methyl shikimate
title_short Tris[(6S)-6-hy­droxy-4-epi-shikimic acid] monohydrate: an enanti­omerically pure hy­droxy­lated shikimic acid derived from methyl shikimate
title_sort tris[(6s)-6-hy­droxy-4-epi-shikimic acid] monohydrate: an enanti­omerically pure hy­droxy­lated shikimic acid derived from methyl shikimate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515248/
https://www.ncbi.nlm.nih.gov/pubmed/23284468
http://dx.doi.org/10.1107/S1600536812041256
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