(3-Oxo-3H-benzo[f]chromen-1-yl)methyl piperidine-1-carbodithio­ate

In the title compound, C(20)H(19)N O(2)S(2),the 3Hbenzo-chromene ring system is nearly planar, with a maximum deviation of 0.036 (2) Å, and the piperidine ring adopts a chair conformation: the bond-angle sum for its N atom is 358.7°. The dihedral angle between the 3H-benzo[f]chromene ring and the pi...

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Autores principales: Kotresh, O., Kumar, K. Mahesh, Mahabaleshwaraiah, N. M., Arunkashi, H. K., Devarajegowda, H. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515261/
https://www.ncbi.nlm.nih.gov/pubmed/23284481
http://dx.doi.org/10.1107/S1600536812042870
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author Kotresh, O.
Kumar, K. Mahesh
Mahabaleshwaraiah, N. M.
Arunkashi, H. K.
Devarajegowda, H. C.
author_facet Kotresh, O.
Kumar, K. Mahesh
Mahabaleshwaraiah, N. M.
Arunkashi, H. K.
Devarajegowda, H. C.
author_sort Kotresh, O.
collection PubMed
description In the title compound, C(20)H(19)N O(2)S(2),the 3Hbenzo-chromene ring system is nearly planar, with a maximum deviation of 0.036 (2) Å, and the piperidine ring adopts a chair conformation: the bond-angle sum for its N atom is 358.7°. The dihedral angle between the 3H-benzo[f]chromene ring and the piperidine ring is 89.07 (8)°. In the crystal, C—H⋯O hydrogen bonds lead to [010] C(6) chains and weak aromatic π–π inter­actions between the fused pyran ring and fused benzene ring of benzochromene [centroid–centroid distance = 3.652 (1) Å] are also observed.
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spelling pubmed-35152612013-01-02 (3-Oxo-3H-benzo[f]chromen-1-yl)methyl piperidine-1-carbodithio­ate Kotresh, O. Kumar, K. Mahesh Mahabaleshwaraiah, N. M. Arunkashi, H. K. Devarajegowda, H. C. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(19)N O(2)S(2),the 3Hbenzo-chromene ring system is nearly planar, with a maximum deviation of 0.036 (2) Å, and the piperidine ring adopts a chair conformation: the bond-angle sum for its N atom is 358.7°. The dihedral angle between the 3H-benzo[f]chromene ring and the piperidine ring is 89.07 (8)°. In the crystal, C—H⋯O hydrogen bonds lead to [010] C(6) chains and weak aromatic π–π inter­actions between the fused pyran ring and fused benzene ring of benzochromene [centroid–centroid distance = 3.652 (1) Å] are also observed. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515261/ /pubmed/23284481 http://dx.doi.org/10.1107/S1600536812042870 Text en © Kotresh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kotresh, O.
Kumar, K. Mahesh
Mahabaleshwaraiah, N. M.
Arunkashi, H. K.
Devarajegowda, H. C.
(3-Oxo-3H-benzo[f]chromen-1-yl)methyl piperidine-1-carbodithio­ate
title (3-Oxo-3H-benzo[f]chromen-1-yl)methyl piperidine-1-carbodithio­ate
title_full (3-Oxo-3H-benzo[f]chromen-1-yl)methyl piperidine-1-carbodithio­ate
title_fullStr (3-Oxo-3H-benzo[f]chromen-1-yl)methyl piperidine-1-carbodithio­ate
title_full_unstemmed (3-Oxo-3H-benzo[f]chromen-1-yl)methyl piperidine-1-carbodithio­ate
title_short (3-Oxo-3H-benzo[f]chromen-1-yl)methyl piperidine-1-carbodithio­ate
title_sort (3-oxo-3h-benzo[f]chromen-1-yl)methyl piperidine-1-carbodithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515261/
https://www.ncbi.nlm.nih.gov/pubmed/23284481
http://dx.doi.org/10.1107/S1600536812042870
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