4-Bromo-2-[(E)-{[4-nitro-2-(trifluoro­meth­yl)phen­yl]imino}­meth­yl]phenol

Except two F atoms of the –CF(3) group, the title compound, C(14)H(8)BrF(3)N(2)O(3), has an almost planar conformation, the dihedral angle between the aromatic rings being 3.60 (16)°. The mol­ecule adopts the enol–imine tautomeric form, with an intra­molecular O—H⋯N hydrogen bond, which generates an...

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Autores principales: Akkurt, Mehmet, Kennedy, Alan R., Mohamed, Shaaban K., Abdelhamid, Antar A., Miller, Gary J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515262/
https://www.ncbi.nlm.nih.gov/pubmed/23284482
http://dx.doi.org/10.1107/S1600536812042262
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author Akkurt, Mehmet
Kennedy, Alan R.
Mohamed, Shaaban K.
Abdelhamid, Antar A.
Miller, Gary J.
author_facet Akkurt, Mehmet
Kennedy, Alan R.
Mohamed, Shaaban K.
Abdelhamid, Antar A.
Miller, Gary J.
author_sort Akkurt, Mehmet
collection PubMed
description Except two F atoms of the –CF(3) group, the title compound, C(14)H(8)BrF(3)N(2)O(3), has an almost planar conformation, the dihedral angle between the aromatic rings being 3.60 (16)°. The mol­ecule adopts the enol–imine tautomeric form, with an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. In the crystal, face-to-face π–π stacking [centroid–centroid distances = 3.669 (2) and 3.732 (2) Å] between the aromatic rings of the mol­ecules, which lie in sheets parallel to (202), help to establish the packing.
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spelling pubmed-35152622013-01-02 4-Bromo-2-[(E)-{[4-nitro-2-(trifluoro­meth­yl)phen­yl]imino}­meth­yl]phenol Akkurt, Mehmet Kennedy, Alan R. Mohamed, Shaaban K. Abdelhamid, Antar A. Miller, Gary J. Acta Crystallogr Sect E Struct Rep Online Organic Papers Except two F atoms of the –CF(3) group, the title compound, C(14)H(8)BrF(3)N(2)O(3), has an almost planar conformation, the dihedral angle between the aromatic rings being 3.60 (16)°. The mol­ecule adopts the enol–imine tautomeric form, with an intra­molecular O—H⋯N hydrogen bond, which generates an S(6) ring motif. In the crystal, face-to-face π–π stacking [centroid–centroid distances = 3.669 (2) and 3.732 (2) Å] between the aromatic rings of the mol­ecules, which lie in sheets parallel to (202), help to establish the packing. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515262/ /pubmed/23284482 http://dx.doi.org/10.1107/S1600536812042262 Text en © Akkurt et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Kennedy, Alan R.
Mohamed, Shaaban K.
Abdelhamid, Antar A.
Miller, Gary J.
4-Bromo-2-[(E)-{[4-nitro-2-(trifluoro­meth­yl)phen­yl]imino}­meth­yl]phenol
title 4-Bromo-2-[(E)-{[4-nitro-2-(trifluoro­meth­yl)phen­yl]imino}­meth­yl]phenol
title_full 4-Bromo-2-[(E)-{[4-nitro-2-(trifluoro­meth­yl)phen­yl]imino}­meth­yl]phenol
title_fullStr 4-Bromo-2-[(E)-{[4-nitro-2-(trifluoro­meth­yl)phen­yl]imino}­meth­yl]phenol
title_full_unstemmed 4-Bromo-2-[(E)-{[4-nitro-2-(trifluoro­meth­yl)phen­yl]imino}­meth­yl]phenol
title_short 4-Bromo-2-[(E)-{[4-nitro-2-(trifluoro­meth­yl)phen­yl]imino}­meth­yl]phenol
title_sort 4-bromo-2-[(e)-{[4-nitro-2-(trifluoro­meth­yl)phen­yl]imino}­meth­yl]phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515262/
https://www.ncbi.nlm.nih.gov/pubmed/23284482
http://dx.doi.org/10.1107/S1600536812042262
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