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Cyclo­(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43

The title compound [systematic name: (3S,8aS)-3-isopropyl­hexa­hydro­pyrrolo­[1,2-a]pyrazine-1,4-dione], C(10)H(16)N(2)O(2),, is a newly isolated cyclic dipeptide from Burkholderia thailandensis MSMB43. There are two independent mol­ecules in the asymmetric unit. Two C atoms and their attached H ato...

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Detalles Bibliográficos
Autores principales: Liu, Xiang-Yang, Wang, Cheng, Cheng, Yi-Qiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515274/
https://www.ncbi.nlm.nih.gov/pubmed/23284494
http://dx.doi.org/10.1107/S1600536812043000
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author Liu, Xiang-Yang
Wang, Cheng
Cheng, Yi-Qiang
author_facet Liu, Xiang-Yang
Wang, Cheng
Cheng, Yi-Qiang
author_sort Liu, Xiang-Yang
collection PubMed
description The title compound [systematic name: (3S,8aS)-3-isopropyl­hexa­hydro­pyrrolo­[1,2-a]pyrazine-1,4-dione], C(10)H(16)N(2)O(2),, is a newly isolated cyclic dipeptide from Burkholderia thailandensis MSMB43. There are two independent mol­ecules in the asymmetric unit. Two C atoms and their attached H atoms in the five-membered ring of one of the mol­ecules are disordered over two sets of sites in a 0.715 (5):0.285 (5) ratio. The two independent mol­ecules have the same configuration and the absolute configurations of the chiral centers were determined based on the observation of anomalous dispersion. In the crystal, two types of N—H⋯O hydrogen bonds link pairs of independent mol­ecules.
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spelling pubmed-35152742013-01-02 Cyclo­(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43 Liu, Xiang-Yang Wang, Cheng Cheng, Yi-Qiang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound [systematic name: (3S,8aS)-3-isopropyl­hexa­hydro­pyrrolo­[1,2-a]pyrazine-1,4-dione], C(10)H(16)N(2)O(2),, is a newly isolated cyclic dipeptide from Burkholderia thailandensis MSMB43. There are two independent mol­ecules in the asymmetric unit. Two C atoms and their attached H atoms in the five-membered ring of one of the mol­ecules are disordered over two sets of sites in a 0.715 (5):0.285 (5) ratio. The two independent mol­ecules have the same configuration and the absolute configurations of the chiral centers were determined based on the observation of anomalous dispersion. In the crystal, two types of N—H⋯O hydrogen bonds link pairs of independent mol­ecules. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515274/ /pubmed/23284494 http://dx.doi.org/10.1107/S1600536812043000 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Xiang-Yang
Wang, Cheng
Cheng, Yi-Qiang
Cyclo­(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43
title Cyclo­(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43
title_full Cyclo­(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43
title_fullStr Cyclo­(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43
title_full_unstemmed Cyclo­(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43
title_short Cyclo­(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43
title_sort cyclo­(-l-prolyl-l-valinyl-) from burkholderia thailandensis msmb43
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515274/
https://www.ncbi.nlm.nih.gov/pubmed/23284494
http://dx.doi.org/10.1107/S1600536812043000
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