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Cyclo(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43
The title compound [systematic name: (3S,8aS)-3-isopropylhexahydropyrrolo[1,2-a]pyrazine-1,4-dione], C(10)H(16)N(2)O(2),, is a newly isolated cyclic dipeptide from Burkholderia thailandensis MSMB43. There are two independent molecules in the asymmetric unit. Two C atoms and their attached H ato...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515274/ https://www.ncbi.nlm.nih.gov/pubmed/23284494 http://dx.doi.org/10.1107/S1600536812043000 |
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author | Liu, Xiang-Yang Wang, Cheng Cheng, Yi-Qiang |
author_facet | Liu, Xiang-Yang Wang, Cheng Cheng, Yi-Qiang |
author_sort | Liu, Xiang-Yang |
collection | PubMed |
description | The title compound [systematic name: (3S,8aS)-3-isopropylhexahydropyrrolo[1,2-a]pyrazine-1,4-dione], C(10)H(16)N(2)O(2),, is a newly isolated cyclic dipeptide from Burkholderia thailandensis MSMB43. There are two independent molecules in the asymmetric unit. Two C atoms and their attached H atoms in the five-membered ring of one of the molecules are disordered over two sets of sites in a 0.715 (5):0.285 (5) ratio. The two independent molecules have the same configuration and the absolute configurations of the chiral centers were determined based on the observation of anomalous dispersion. In the crystal, two types of N—H⋯O hydrogen bonds link pairs of independent molecules. |
format | Online Article Text |
id | pubmed-3515274 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35152742013-01-02 Cyclo(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43 Liu, Xiang-Yang Wang, Cheng Cheng, Yi-Qiang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound [systematic name: (3S,8aS)-3-isopropylhexahydropyrrolo[1,2-a]pyrazine-1,4-dione], C(10)H(16)N(2)O(2),, is a newly isolated cyclic dipeptide from Burkholderia thailandensis MSMB43. There are two independent molecules in the asymmetric unit. Two C atoms and their attached H atoms in the five-membered ring of one of the molecules are disordered over two sets of sites in a 0.715 (5):0.285 (5) ratio. The two independent molecules have the same configuration and the absolute configurations of the chiral centers were determined based on the observation of anomalous dispersion. In the crystal, two types of N—H⋯O hydrogen bonds link pairs of independent molecules. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515274/ /pubmed/23284494 http://dx.doi.org/10.1107/S1600536812043000 Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Liu, Xiang-Yang Wang, Cheng Cheng, Yi-Qiang Cyclo(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43 |
title | Cyclo(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43 |
title_full | Cyclo(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43 |
title_fullStr | Cyclo(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43 |
title_full_unstemmed | Cyclo(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43 |
title_short | Cyclo(-l-prolyl-l-valinyl-) from Burkholderia thailandensis MSMB43 |
title_sort | cyclo(-l-prolyl-l-valinyl-) from burkholderia thailandensis msmb43 |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515274/ https://www.ncbi.nlm.nih.gov/pubmed/23284494 http://dx.doi.org/10.1107/S1600536812043000 |
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