(+)-(1S,5R,6R)-6-[(S)-1-Hy­droxy-2-(meth­oxy­meth­yloxy)eth­yl]-1-methyl-3-trichloro­methyl-2-aza-4,7-dioxa­bicyclo­[3.3.0]oct-2-en-8-one

In the title compound, C(11)H(14)Cl(3)NO(6), the fused five-membered oxazoline and tetra­hydro­furan rings are essentially planar with maximum deviations of 0.069 (1) and 0.031 (1) Å, respectively, and make a dihedral angle of 64.23 (11)° with each other. In the crystal, mol­ecules are linked by O—H...

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Detalles Bibliográficos
Autores principales: Oishi, Takeshi, Oishi, Hiroki, Tsuzaki, Syun, Sato, Takaaki, Chida, Noritaka
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515276/
https://www.ncbi.nlm.nih.gov/pubmed/23284496
http://dx.doi.org/10.1107/S1600536812042912
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author Oishi, Takeshi
Oishi, Hiroki
Tsuzaki, Syun
Sato, Takaaki
Chida, Noritaka
author_facet Oishi, Takeshi
Oishi, Hiroki
Tsuzaki, Syun
Sato, Takaaki
Chida, Noritaka
author_sort Oishi, Takeshi
collection PubMed
description In the title compound, C(11)H(14)Cl(3)NO(6), the fused five-membered oxazoline and tetra­hydro­furan rings are essentially planar with maximum deviations of 0.069 (1) and 0.031 (1) Å, respectively, and make a dihedral angle of 64.23 (11)° with each other. In the crystal, mol­ecules are linked by O—H⋯O and C—H⋯O hydrogen bonds, forming chains along the b-axis direction. Further C—H⋯O hydrogen bonds are observed between the chains.
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spelling pubmed-35152762013-01-02 (+)-(1S,5R,6R)-6-[(S)-1-Hy­droxy-2-(meth­oxy­meth­yloxy)eth­yl]-1-methyl-3-trichloro­methyl-2-aza-4,7-dioxa­bicyclo­[3.3.0]oct-2-en-8-one Oishi, Takeshi Oishi, Hiroki Tsuzaki, Syun Sato, Takaaki Chida, Noritaka Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(14)Cl(3)NO(6), the fused five-membered oxazoline and tetra­hydro­furan rings are essentially planar with maximum deviations of 0.069 (1) and 0.031 (1) Å, respectively, and make a dihedral angle of 64.23 (11)° with each other. In the crystal, mol­ecules are linked by O—H⋯O and C—H⋯O hydrogen bonds, forming chains along the b-axis direction. Further C—H⋯O hydrogen bonds are observed between the chains. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515276/ /pubmed/23284496 http://dx.doi.org/10.1107/S1600536812042912 Text en © Oishi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Oishi, Takeshi
Oishi, Hiroki
Tsuzaki, Syun
Sato, Takaaki
Chida, Noritaka
(+)-(1S,5R,6R)-6-[(S)-1-Hy­droxy-2-(meth­oxy­meth­yloxy)eth­yl]-1-methyl-3-trichloro­methyl-2-aza-4,7-dioxa­bicyclo­[3.3.0]oct-2-en-8-one
title (+)-(1S,5R,6R)-6-[(S)-1-Hy­droxy-2-(meth­oxy­meth­yloxy)eth­yl]-1-methyl-3-trichloro­methyl-2-aza-4,7-dioxa­bicyclo­[3.3.0]oct-2-en-8-one
title_full (+)-(1S,5R,6R)-6-[(S)-1-Hy­droxy-2-(meth­oxy­meth­yloxy)eth­yl]-1-methyl-3-trichloro­methyl-2-aza-4,7-dioxa­bicyclo­[3.3.0]oct-2-en-8-one
title_fullStr (+)-(1S,5R,6R)-6-[(S)-1-Hy­droxy-2-(meth­oxy­meth­yloxy)eth­yl]-1-methyl-3-trichloro­methyl-2-aza-4,7-dioxa­bicyclo­[3.3.0]oct-2-en-8-one
title_full_unstemmed (+)-(1S,5R,6R)-6-[(S)-1-Hy­droxy-2-(meth­oxy­meth­yloxy)eth­yl]-1-methyl-3-trichloro­methyl-2-aza-4,7-dioxa­bicyclo­[3.3.0]oct-2-en-8-one
title_short (+)-(1S,5R,6R)-6-[(S)-1-Hy­droxy-2-(meth­oxy­meth­yloxy)eth­yl]-1-methyl-3-trichloro­methyl-2-aza-4,7-dioxa­bicyclo­[3.3.0]oct-2-en-8-one
title_sort (+)-(1s,5r,6r)-6-[(s)-1-hy­droxy-2-(meth­oxy­meth­yloxy)eth­yl]-1-methyl-3-trichloro­methyl-2-aza-4,7-dioxa­bicyclo­[3.3.0]oct-2-en-8-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515276/
https://www.ncbi.nlm.nih.gov/pubmed/23284496
http://dx.doi.org/10.1107/S1600536812042912
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