N,N,N′,N′-Tetra­benzyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide

In the C(O)NHP(O) fragment of the title compound, C(35)H(32)F(2)N(3)O(2)P, the P—N bond is longer and the O—P—N angle is contracted compared with the other two P—N bonds and O—P—N angles. The P atom adopts a distorted tetra­hedral environment and the phosphoryl and carbonyl groups are anti with resp...

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Detalles Bibliográficos
Autores principales: Raissi Shabari, Akbar, Pourayoubi, Mehrdad, Tarahhomi, Atekeh, Rheingold, Arnold L., Golen, James A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515277/
https://www.ncbi.nlm.nih.gov/pubmed/23284497
http://dx.doi.org/10.1107/S1600536812042481
Descripción
Sumario:In the C(O)NHP(O) fragment of the title compound, C(35)H(32)F(2)N(3)O(2)P, the P—N bond is longer and the O—P—N angle is contracted compared with the other two P—N bonds and O—P—N angles. The P atom adopts a distorted tetra­hedral environment and the phosphoryl and carbonyl groups are anti with respect to each other. The two tertiary N atoms of the dibenzyl­amido groups show sp (2) character with a slight deviation from planarity. In the crystal, pairs of N—H⋯O(P) hydrogen bonds form inversion dimers.

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