N,N,N′,N′-Tetra­benzyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide

In the C(O)NHP(O) fragment of the title compound, C(35)H(32)F(2)N(3)O(2)P, the P—N bond is longer and the O—P—N angle is contracted compared with the other two P—N bonds and O—P—N angles. The P atom adopts a distorted tetra­hedral environment and the phosphoryl and carbonyl groups are anti with resp...

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Detalles Bibliográficos
Autores principales: Raissi Shabari, Akbar, Pourayoubi, Mehrdad, Tarahhomi, Atekeh, Rheingold, Arnold L., Golen, James A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515277/
https://www.ncbi.nlm.nih.gov/pubmed/23284497
http://dx.doi.org/10.1107/S1600536812042481
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author Raissi Shabari, Akbar
Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
author_facet Raissi Shabari, Akbar
Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
author_sort Raissi Shabari, Akbar
collection PubMed
description In the C(O)NHP(O) fragment of the title compound, C(35)H(32)F(2)N(3)O(2)P, the P—N bond is longer and the O—P—N angle is contracted compared with the other two P—N bonds and O—P—N angles. The P atom adopts a distorted tetra­hedral environment and the phosphoryl and carbonyl groups are anti with respect to each other. The two tertiary N atoms of the dibenzyl­amido groups show sp (2) character with a slight deviation from planarity. In the crystal, pairs of N—H⋯O(P) hydrogen bonds form inversion dimers.
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spelling pubmed-35152772013-01-02 N,N,N′,N′-Tetra­benzyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide Raissi Shabari, Akbar Pourayoubi, Mehrdad Tarahhomi, Atekeh Rheingold, Arnold L. Golen, James A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the C(O)NHP(O) fragment of the title compound, C(35)H(32)F(2)N(3)O(2)P, the P—N bond is longer and the O—P—N angle is contracted compared with the other two P—N bonds and O—P—N angles. The P atom adopts a distorted tetra­hedral environment and the phosphoryl and carbonyl groups are anti with respect to each other. The two tertiary N atoms of the dibenzyl­amido groups show sp (2) character with a slight deviation from planarity. In the crystal, pairs of N—H⋯O(P) hydrogen bonds form inversion dimers. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515277/ /pubmed/23284497 http://dx.doi.org/10.1107/S1600536812042481 Text en © Raissi Shabari et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Raissi Shabari, Akbar
Pourayoubi, Mehrdad
Tarahhomi, Atekeh
Rheingold, Arnold L.
Golen, James A.
N,N,N′,N′-Tetra­benzyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide
title N,N,N′,N′-Tetra­benzyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide
title_full N,N,N′,N′-Tetra­benzyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide
title_fullStr N,N,N′,N′-Tetra­benzyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide
title_full_unstemmed N,N,N′,N′-Tetra­benzyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide
title_short N,N,N′,N′-Tetra­benzyl-N′′-(2,6-difluoro­benzo­yl)phospho­ric triamide
title_sort n,n,n′,n′-tetra­benzyl-n′′-(2,6-difluoro­benzo­yl)phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515277/
https://www.ncbi.nlm.nih.gov/pubmed/23284497
http://dx.doi.org/10.1107/S1600536812042481
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