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N-(2,3-Dimethylphenyl)-2-nitrobenzenesulfonamide
There are two independent molecules in the asymmetric unit of the title compound, C(14)H(14)N(2)O(4)S. The N—H bonds are syn to the ortho-nitro groups in the sulfonyl benzene rings and anti to the methyl groups in the aniline benzene rings. The molecules are twisted at the S—N bonds with torsion a...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515279/ https://www.ncbi.nlm.nih.gov/pubmed/23284499 http://dx.doi.org/10.1107/S1600536812042845 |
Sumario: | There are two independent molecules in the asymmetric unit of the title compound, C(14)H(14)N(2)O(4)S. The N—H bonds are syn to the ortho-nitro groups in the sulfonyl benzene rings and anti to the methyl groups in the aniline benzene rings. The molecules are twisted at the S—N bonds with torsion angles of −60.4 (3) and 58.8 (3)° in the two molecules. The dihedral angles between the planes of the sulfonyl and the anilino benzene rings are 53.67 (8) and 56.99 (9)°. The amide H atoms of both molecules are involved in an intramolecular hydrogen bond, generating an S(7) motif. In the crystal, pairs of N—H⋯O(S) hydrogen bonds link like molecules into inversion dimers. |
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