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N-(2,3-Dimethyl­phen­yl)-2-nitro­benzene­sulfonamide

There are two independent mol­ecules in the asymmetric unit of the title compound, C(14)H(14)N(2)O(4)S. The N—H bonds are syn to the ortho-nitro groups in the sulfonyl benzene rings and anti to the methyl groups in the aniline benzene rings. The mol­ecules are twisted at the S—N bonds with torsion a...

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Detalles Bibliográficos
Autores principales: Chaithanya, U., Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515279/
https://www.ncbi.nlm.nih.gov/pubmed/23284499
http://dx.doi.org/10.1107/S1600536812042845
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author Chaithanya, U.
Foro, Sabine
Gowda, B. Thimme
author_facet Chaithanya, U.
Foro, Sabine
Gowda, B. Thimme
author_sort Chaithanya, U.
collection PubMed
description There are two independent mol­ecules in the asymmetric unit of the title compound, C(14)H(14)N(2)O(4)S. The N—H bonds are syn to the ortho-nitro groups in the sulfonyl benzene rings and anti to the methyl groups in the aniline benzene rings. The mol­ecules are twisted at the S—N bonds with torsion angles of −60.4 (3) and 58.8 (3)° in the two mol­ecules. The dihedral angles between the planes of the sulfonyl and the anilino benzene rings are 53.67 (8) and 56.99 (9)°. The amide H atoms of both mol­ecules are involved in an intra­molecular hydrogen bond, generating an S(7) motif. In the crystal, pairs of N—H⋯O(S) hydrogen bonds link like mol­ecules into inversion dimers.
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spelling pubmed-35152792013-01-02 N-(2,3-Dimethyl­phen­yl)-2-nitro­benzene­sulfonamide Chaithanya, U. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent mol­ecules in the asymmetric unit of the title compound, C(14)H(14)N(2)O(4)S. The N—H bonds are syn to the ortho-nitro groups in the sulfonyl benzene rings and anti to the methyl groups in the aniline benzene rings. The mol­ecules are twisted at the S—N bonds with torsion angles of −60.4 (3) and 58.8 (3)° in the two mol­ecules. The dihedral angles between the planes of the sulfonyl and the anilino benzene rings are 53.67 (8) and 56.99 (9)°. The amide H atoms of both mol­ecules are involved in an intra­molecular hydrogen bond, generating an S(7) motif. In the crystal, pairs of N—H⋯O(S) hydrogen bonds link like mol­ecules into inversion dimers. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515279/ /pubmed/23284499 http://dx.doi.org/10.1107/S1600536812042845 Text en © Chaithanya et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chaithanya, U.
Foro, Sabine
Gowda, B. Thimme
N-(2,3-Dimethyl­phen­yl)-2-nitro­benzene­sulfonamide
title N-(2,3-Dimethyl­phen­yl)-2-nitro­benzene­sulfonamide
title_full N-(2,3-Dimethyl­phen­yl)-2-nitro­benzene­sulfonamide
title_fullStr N-(2,3-Dimethyl­phen­yl)-2-nitro­benzene­sulfonamide
title_full_unstemmed N-(2,3-Dimethyl­phen­yl)-2-nitro­benzene­sulfonamide
title_short N-(2,3-Dimethyl­phen­yl)-2-nitro­benzene­sulfonamide
title_sort n-(2,3-dimethyl­phen­yl)-2-nitro­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515279/
https://www.ncbi.nlm.nih.gov/pubmed/23284499
http://dx.doi.org/10.1107/S1600536812042845
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