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N-(2,3-Dimethylphenyl)-2-nitrobenzenesulfonamide
There are two independent molecules in the asymmetric unit of the title compound, C(14)H(14)N(2)O(4)S. The N—H bonds are syn to the ortho-nitro groups in the sulfonyl benzene rings and anti to the methyl groups in the aniline benzene rings. The molecules are twisted at the S—N bonds with torsion a...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515279/ https://www.ncbi.nlm.nih.gov/pubmed/23284499 http://dx.doi.org/10.1107/S1600536812042845 |
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author | Chaithanya, U. Foro, Sabine Gowda, B. Thimme |
author_facet | Chaithanya, U. Foro, Sabine Gowda, B. Thimme |
author_sort | Chaithanya, U. |
collection | PubMed |
description | There are two independent molecules in the asymmetric unit of the title compound, C(14)H(14)N(2)O(4)S. The N—H bonds are syn to the ortho-nitro groups in the sulfonyl benzene rings and anti to the methyl groups in the aniline benzene rings. The molecules are twisted at the S—N bonds with torsion angles of −60.4 (3) and 58.8 (3)° in the two molecules. The dihedral angles between the planes of the sulfonyl and the anilino benzene rings are 53.67 (8) and 56.99 (9)°. The amide H atoms of both molecules are involved in an intramolecular hydrogen bond, generating an S(7) motif. In the crystal, pairs of N—H⋯O(S) hydrogen bonds link like molecules into inversion dimers. |
format | Online Article Text |
id | pubmed-3515279 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35152792013-01-02 N-(2,3-Dimethylphenyl)-2-nitrobenzenesulfonamide Chaithanya, U. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent molecules in the asymmetric unit of the title compound, C(14)H(14)N(2)O(4)S. The N—H bonds are syn to the ortho-nitro groups in the sulfonyl benzene rings and anti to the methyl groups in the aniline benzene rings. The molecules are twisted at the S—N bonds with torsion angles of −60.4 (3) and 58.8 (3)° in the two molecules. The dihedral angles between the planes of the sulfonyl and the anilino benzene rings are 53.67 (8) and 56.99 (9)°. The amide H atoms of both molecules are involved in an intramolecular hydrogen bond, generating an S(7) motif. In the crystal, pairs of N—H⋯O(S) hydrogen bonds link like molecules into inversion dimers. International Union of Crystallography 2012-10-20 /pmc/articles/PMC3515279/ /pubmed/23284499 http://dx.doi.org/10.1107/S1600536812042845 Text en © Chaithanya et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chaithanya, U. Foro, Sabine Gowda, B. Thimme N-(2,3-Dimethylphenyl)-2-nitrobenzenesulfonamide |
title |
N-(2,3-Dimethylphenyl)-2-nitrobenzenesulfonamide |
title_full |
N-(2,3-Dimethylphenyl)-2-nitrobenzenesulfonamide |
title_fullStr |
N-(2,3-Dimethylphenyl)-2-nitrobenzenesulfonamide |
title_full_unstemmed |
N-(2,3-Dimethylphenyl)-2-nitrobenzenesulfonamide |
title_short |
N-(2,3-Dimethylphenyl)-2-nitrobenzenesulfonamide |
title_sort | n-(2,3-dimethylphenyl)-2-nitrobenzenesulfonamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515279/ https://www.ncbi.nlm.nih.gov/pubmed/23284499 http://dx.doi.org/10.1107/S1600536812042845 |
work_keys_str_mv | AT chaithanyau n23dimethylphenyl2nitrobenzenesulfonamide AT forosabine n23dimethylphenyl2nitrobenzenesulfonamide AT gowdabthimme n23dimethylphenyl2nitrobenzenesulfonamide |