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2-Amino-5-methyl­pyridinium 2-amino­benzoate

In the 2-amino­benzoate anion of the title salt, C(6)H(9)N(2) (+)·C(7)H(6)NO(2) (−), an intra­molecular N—H⋯O hydrogen bond is observed. The dihedral angle between the ring and the CO(2) group is 8.41 (13)°. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonde...

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Autores principales: Thanigaimani, Kaliyaperumal, Farhadikoutenaei, Abbas, Khalib, Nuridayanti Che, Arshad, Suhana, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515287/
https://www.ncbi.nlm.nih.gov/pubmed/23284507
http://dx.doi.org/10.1107/S1600536812043243
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author Thanigaimani, Kaliyaperumal
Farhadikoutenaei, Abbas
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
author_facet Thanigaimani, Kaliyaperumal
Farhadikoutenaei, Abbas
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
author_sort Thanigaimani, Kaliyaperumal
collection PubMed
description In the 2-amino­benzoate anion of the title salt, C(6)H(9)N(2) (+)·C(7)H(6)NO(2) (−), an intra­molecular N—H⋯O hydrogen bond is observed. The dihedral angle between the ring and the CO(2) group is 8.41 (13)°. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are further connected via N—H⋯O hydrogen bonds, resulting in a donor–donor–acceptor–acceptor (DDAA) array of quadruple hydrogen bonds. The crystal structure also features a weak N—H⋯O hydrogen bond and a C—H⋯π inter­action, resulting in a three-dimensional network.
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spelling pubmed-35152872013-01-02 2-Amino-5-methyl­pyridinium 2-amino­benzoate Thanigaimani, Kaliyaperumal Farhadikoutenaei, Abbas Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the 2-amino­benzoate anion of the title salt, C(6)H(9)N(2) (+)·C(7)H(6)NO(2) (−), an intra­molecular N—H⋯O hydrogen bond is observed. The dihedral angle between the ring and the CO(2) group is 8.41 (13)°. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are further connected via N—H⋯O hydrogen bonds, resulting in a donor–donor–acceptor–acceptor (DDAA) array of quadruple hydrogen bonds. The crystal structure also features a weak N—H⋯O hydrogen bond and a C—H⋯π inter­action, resulting in a three-dimensional network. International Union of Crystallography 2012-10-24 /pmc/articles/PMC3515287/ /pubmed/23284507 http://dx.doi.org/10.1107/S1600536812043243 Text en © Thanigaimani et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thanigaimani, Kaliyaperumal
Farhadikoutenaei, Abbas
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
2-Amino-5-methyl­pyridinium 2-amino­benzoate
title 2-Amino-5-methyl­pyridinium 2-amino­benzoate
title_full 2-Amino-5-methyl­pyridinium 2-amino­benzoate
title_fullStr 2-Amino-5-methyl­pyridinium 2-amino­benzoate
title_full_unstemmed 2-Amino-5-methyl­pyridinium 2-amino­benzoate
title_short 2-Amino-5-methyl­pyridinium 2-amino­benzoate
title_sort 2-amino-5-methyl­pyridinium 2-amino­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515287/
https://www.ncbi.nlm.nih.gov/pubmed/23284507
http://dx.doi.org/10.1107/S1600536812043243
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