Cargando…
2-Amino-5-methylpyridinium 2-aminobenzoate
In the 2-aminobenzoate anion of the title salt, C(6)H(9)N(2) (+)·C(7)H(6)NO(2) (−), an intramolecular N—H⋯O hydrogen bond is observed. The dihedral angle between the ring and the CO(2) group is 8.41 (13)°. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonde...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515287/ https://www.ncbi.nlm.nih.gov/pubmed/23284507 http://dx.doi.org/10.1107/S1600536812043243 |
_version_ | 1782252152188567552 |
---|---|
author | Thanigaimani, Kaliyaperumal Farhadikoutenaei, Abbas Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul |
author_facet | Thanigaimani, Kaliyaperumal Farhadikoutenaei, Abbas Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul |
author_sort | Thanigaimani, Kaliyaperumal |
collection | PubMed |
description | In the 2-aminobenzoate anion of the title salt, C(6)H(9)N(2) (+)·C(7)H(6)NO(2) (−), an intramolecular N—H⋯O hydrogen bond is observed. The dihedral angle between the ring and the CO(2) group is 8.41 (13)°. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are further connected via N—H⋯O hydrogen bonds, resulting in a donor–donor–acceptor–acceptor (DDAA) array of quadruple hydrogen bonds. The crystal structure also features a weak N—H⋯O hydrogen bond and a C—H⋯π interaction, resulting in a three-dimensional network. |
format | Online Article Text |
id | pubmed-3515287 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35152872013-01-02 2-Amino-5-methylpyridinium 2-aminobenzoate Thanigaimani, Kaliyaperumal Farhadikoutenaei, Abbas Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the 2-aminobenzoate anion of the title salt, C(6)H(9)N(2) (+)·C(7)H(6)NO(2) (−), an intramolecular N—H⋯O hydrogen bond is observed. The dihedral angle between the ring and the CO(2) group is 8.41 (13)°. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The ion pairs are further connected via N—H⋯O hydrogen bonds, resulting in a donor–donor–acceptor–acceptor (DDAA) array of quadruple hydrogen bonds. The crystal structure also features a weak N—H⋯O hydrogen bond and a C—H⋯π interaction, resulting in a three-dimensional network. International Union of Crystallography 2012-10-24 /pmc/articles/PMC3515287/ /pubmed/23284507 http://dx.doi.org/10.1107/S1600536812043243 Text en © Thanigaimani et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Thanigaimani, Kaliyaperumal Farhadikoutenaei, Abbas Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul 2-Amino-5-methylpyridinium 2-aminobenzoate |
title | 2-Amino-5-methylpyridinium 2-aminobenzoate |
title_full | 2-Amino-5-methylpyridinium 2-aminobenzoate |
title_fullStr | 2-Amino-5-methylpyridinium 2-aminobenzoate |
title_full_unstemmed | 2-Amino-5-methylpyridinium 2-aminobenzoate |
title_short | 2-Amino-5-methylpyridinium 2-aminobenzoate |
title_sort | 2-amino-5-methylpyridinium 2-aminobenzoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515287/ https://www.ncbi.nlm.nih.gov/pubmed/23284507 http://dx.doi.org/10.1107/S1600536812043243 |
work_keys_str_mv | AT thanigaimanikaliyaperumal 2amino5methylpyridinium2aminobenzoate AT farhadikoutenaeiabbas 2amino5methylpyridinium2aminobenzoate AT khalibnuridayantiche 2amino5methylpyridinium2aminobenzoate AT arshadsuhana 2amino5methylpyridinium2aminobenzoate AT razakibrahimabdul 2amino5methylpyridinium2aminobenzoate |