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[4-(Bromomethyl)benzyl]triphenylphosphonium bromide acetonitrile monosolvate
In the title compound, C(26)H(23)BrP(+)·Br(−)·C(2)H(3)N, the dihedral angles between the plane of the benzylic phenyl ring attached to the P atom and the planes of the three directly attached phenyl rings are 34.04 (12), 45.48 (13) and 87.18 (9)°. In the crystal, centrosymmetric pairs of cations and...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515291/ https://www.ncbi.nlm.nih.gov/pubmed/23284511 http://dx.doi.org/10.1107/S1600536812042341 |
| Sumario: | In the title compound, C(26)H(23)BrP(+)·Br(−)·C(2)H(3)N, the dihedral angles between the plane of the benzylic phenyl ring attached to the P atom and the planes of the three directly attached phenyl rings are 34.04 (12), 45.48 (13) and 87.18 (9)°. In the crystal, centrosymmetric pairs of cations and anions are linked into dimeric aggregates via C—H⋯Br hydrogen bonds. There is also a C—H⋯N hydrogen bond to the acetonitrile solvent molecule. |
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