[4-(Bromo­methyl)­benz­yl]triphenyl­phospho­nium bromide acetonitrile monosolvate

In the title compound, C(26)H(23)BrP(+)·Br(−)·C(2)H(3)N, the dihedral angles between the plane of the benzylic phenyl ring attached to the P atom and the planes of the three directly attached phenyl rings are 34.04 (12), 45.48 (13) and 87.18 (9)°. In the crystal, centrosymmetric pairs of cations and...

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Detalles Bibliográficos
Autores principales: Burke, Benjamin P., Greenman, Peter, Smith, Adam M., Archibald, Stephen J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515291/
https://www.ncbi.nlm.nih.gov/pubmed/23284511
http://dx.doi.org/10.1107/S1600536812042341
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author Burke, Benjamin P.
Greenman, Peter
Smith, Adam M.
Archibald, Stephen J.
author_facet Burke, Benjamin P.
Greenman, Peter
Smith, Adam M.
Archibald, Stephen J.
author_sort Burke, Benjamin P.
collection PubMed
description In the title compound, C(26)H(23)BrP(+)·Br(−)·C(2)H(3)N, the dihedral angles between the plane of the benzylic phenyl ring attached to the P atom and the planes of the three directly attached phenyl rings are 34.04 (12), 45.48 (13) and 87.18 (9)°. In the crystal, centrosymmetric pairs of cations and anions are linked into dimeric aggregates via C—H⋯Br hydrogen bonds. There is also a C—H⋯N hydrogen bond to the acetonitrile solvent mol­ecule.
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spelling pubmed-35152912013-01-02 [4-(Bromo­methyl)­benz­yl]triphenyl­phospho­nium bromide acetonitrile monosolvate Burke, Benjamin P. Greenman, Peter Smith, Adam M. Archibald, Stephen J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(23)BrP(+)·Br(−)·C(2)H(3)N, the dihedral angles between the plane of the benzylic phenyl ring attached to the P atom and the planes of the three directly attached phenyl rings are 34.04 (12), 45.48 (13) and 87.18 (9)°. In the crystal, centrosymmetric pairs of cations and anions are linked into dimeric aggregates via C—H⋯Br hydrogen bonds. There is also a C—H⋯N hydrogen bond to the acetonitrile solvent mol­ecule. International Union of Crystallography 2012-10-24 /pmc/articles/PMC3515291/ /pubmed/23284511 http://dx.doi.org/10.1107/S1600536812042341 Text en © Burke et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Burke, Benjamin P.
Greenman, Peter
Smith, Adam M.
Archibald, Stephen J.
[4-(Bromo­methyl)­benz­yl]triphenyl­phospho­nium bromide acetonitrile monosolvate
title [4-(Bromo­methyl)­benz­yl]triphenyl­phospho­nium bromide acetonitrile monosolvate
title_full [4-(Bromo­methyl)­benz­yl]triphenyl­phospho­nium bromide acetonitrile monosolvate
title_fullStr [4-(Bromo­methyl)­benz­yl]triphenyl­phospho­nium bromide acetonitrile monosolvate
title_full_unstemmed [4-(Bromo­methyl)­benz­yl]triphenyl­phospho­nium bromide acetonitrile monosolvate
title_short [4-(Bromo­methyl)­benz­yl]triphenyl­phospho­nium bromide acetonitrile monosolvate
title_sort [4-(bromo­methyl)­benz­yl]triphenyl­phospho­nium bromide acetonitrile monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515291/
https://www.ncbi.nlm.nih.gov/pubmed/23284511
http://dx.doi.org/10.1107/S1600536812042341
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