3-(4-Chloro­phen­yl)-5-phenyl-4,5-di­hydro-1,3-oxazole

In the title compound, C(15)H(12)ClNO, the isoxazoline ring adopts an envelope conformation with the C atom bearing an unsubstituted phenyl ring as the flap atom. The chlorinated phenyl group is nearly in-plane with the four coplanar atoms of the heterocycle and the corresponding mean planes enclosi...

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Autores principales: Islor, Arun M., Yaradoni, Rajiv, Garudachari, B., Gerber, Thomas, Hosten, Eric, Betz, Richard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515301/
https://www.ncbi.nlm.nih.gov/pubmed/23284521
http://dx.doi.org/10.1107/S1600536812043711
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author Islor, Arun M.
Yaradoni, Rajiv
Garudachari, B.
Gerber, Thomas
Hosten, Eric
Betz, Richard
author_facet Islor, Arun M.
Yaradoni, Rajiv
Garudachari, B.
Gerber, Thomas
Hosten, Eric
Betz, Richard
author_sort Islor, Arun M.
collection PubMed
description In the title compound, C(15)H(12)ClNO, the isoxazoline ring adopts an envelope conformation with the C atom bearing an unsubstituted phenyl ring as the flap atom. The chlorinated phenyl group is nearly in-plane with the four coplanar atoms of the heterocycle and the corresponding mean planes enclosing an angle of 1.16 (7)°. The unsubstituted phenyl group attached to the envelope flap atom approaches a nearly perpendicular orientation relative to the isoxazoline ring with a dihedral angle of 74.93 (7)°. In the crystal, weak C—H⋯O, C—H⋯N and C—H⋯π inter­actions connect the mol­ecules into layers perpendicular to the a axis.
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spelling pubmed-35153012013-01-02 3-(4-Chloro­phen­yl)-5-phenyl-4,5-di­hydro-1,3-oxazole Islor, Arun M. Yaradoni, Rajiv Garudachari, B. Gerber, Thomas Hosten, Eric Betz, Richard Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(12)ClNO, the isoxazoline ring adopts an envelope conformation with the C atom bearing an unsubstituted phenyl ring as the flap atom. The chlorinated phenyl group is nearly in-plane with the four coplanar atoms of the heterocycle and the corresponding mean planes enclosing an angle of 1.16 (7)°. The unsubstituted phenyl group attached to the envelope flap atom approaches a nearly perpendicular orientation relative to the isoxazoline ring with a dihedral angle of 74.93 (7)°. In the crystal, weak C—H⋯O, C—H⋯N and C—H⋯π inter­actions connect the mol­ecules into layers perpendicular to the a axis. International Union of Crystallography 2012-10-27 /pmc/articles/PMC3515301/ /pubmed/23284521 http://dx.doi.org/10.1107/S1600536812043711 Text en © Islor et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Islor, Arun M.
Yaradoni, Rajiv
Garudachari, B.
Gerber, Thomas
Hosten, Eric
Betz, Richard
3-(4-Chloro­phen­yl)-5-phenyl-4,5-di­hydro-1,3-oxazole
title 3-(4-Chloro­phen­yl)-5-phenyl-4,5-di­hydro-1,3-oxazole
title_full 3-(4-Chloro­phen­yl)-5-phenyl-4,5-di­hydro-1,3-oxazole
title_fullStr 3-(4-Chloro­phen­yl)-5-phenyl-4,5-di­hydro-1,3-oxazole
title_full_unstemmed 3-(4-Chloro­phen­yl)-5-phenyl-4,5-di­hydro-1,3-oxazole
title_short 3-(4-Chloro­phen­yl)-5-phenyl-4,5-di­hydro-1,3-oxazole
title_sort 3-(4-chloro­phen­yl)-5-phenyl-4,5-di­hydro-1,3-oxazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515301/
https://www.ncbi.nlm.nih.gov/pubmed/23284521
http://dx.doi.org/10.1107/S1600536812043711
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AT gerberthomas 34chlorophenyl5phenyl45dihydro13oxazole
AT hosteneric 34chlorophenyl5phenyl45dihydro13oxazole
AT betzrichard 34chlorophenyl5phenyl45dihydro13oxazole

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