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Benzoximate

In the title compound [systematic name: (3-chloro-2,6-dimeth­oxy­phen­yl)(eth­oxy­imino)­methyl benzoate], C(18)H(18)ClNO(5), the phenyl and chloro­dimeth­oxy­phenyl rings are linked by the eth­oxy­imino­methyl benzoate system such that they are almost perpendicular to each other with the dihedral a...

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Detalles Bibliográficos
Autores principales: Kim, Tae Ho, Moon, Suk-Hee, Kim, Jineun, Park, Ki-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515316/
https://www.ncbi.nlm.nih.gov/pubmed/23284536
http://dx.doi.org/10.1107/S1600536812044248
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author Kim, Tae Ho
Moon, Suk-Hee
Kim, Jineun
Park, Ki-Min
author_facet Kim, Tae Ho
Moon, Suk-Hee
Kim, Jineun
Park, Ki-Min
author_sort Kim, Tae Ho
collection PubMed
description In the title compound [systematic name: (3-chloro-2,6-dimeth­oxy­phen­yl)(eth­oxy­imino)­methyl benzoate], C(18)H(18)ClNO(5), the phenyl and chloro­dimeth­oxy­phenyl rings are linked by the eth­oxy­imino­methyl benzoate system such that they are almost perpendicular to each other with the dihedral angle between them being 85.72 (9)°. In the crystal, C—H⋯O and C—H⋯Cl hydrogen bonds between the phenyl and chloro­dimeth­oxy­phenyl rings generate R (2) (2)(8) rings which link the mol­ecules into zigzag chains along the b axis. Additional C—H⋯O contacts, together with weak inter­molecular C—H⋯π inter­actions, further link the mol­ecules into a three-dimensional network.
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spelling pubmed-35153162013-01-02 Benzoximate Kim, Tae Ho Moon, Suk-Hee Kim, Jineun Park, Ki-Min Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound [systematic name: (3-chloro-2,6-dimeth­oxy­phen­yl)(eth­oxy­imino)­methyl benzoate], C(18)H(18)ClNO(5), the phenyl and chloro­dimeth­oxy­phenyl rings are linked by the eth­oxy­imino­methyl benzoate system such that they are almost perpendicular to each other with the dihedral angle between them being 85.72 (9)°. In the crystal, C—H⋯O and C—H⋯Cl hydrogen bonds between the phenyl and chloro­dimeth­oxy­phenyl rings generate R (2) (2)(8) rings which link the mol­ecules into zigzag chains along the b axis. Additional C—H⋯O contacts, together with weak inter­molecular C—H⋯π inter­actions, further link the mol­ecules into a three-dimensional network. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515316/ /pubmed/23284536 http://dx.doi.org/10.1107/S1600536812044248 Text en © Kim et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kim, Tae Ho
Moon, Suk-Hee
Kim, Jineun
Park, Ki-Min
Benzoximate
title Benzoximate
title_full Benzoximate
title_fullStr Benzoximate
title_full_unstemmed Benzoximate
title_short Benzoximate
title_sort benzoximate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515316/
https://www.ncbi.nlm.nih.gov/pubmed/23284536
http://dx.doi.org/10.1107/S1600536812044248
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