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Benzoximate
In the title compound [systematic name: (3-chloro-2,6-dimethoxyphenyl)(ethoxyimino)methyl benzoate], C(18)H(18)ClNO(5), the phenyl and chlorodimethoxyphenyl rings are linked by the ethoxyiminomethyl benzoate system such that they are almost perpendicular to each other with the dihedral a...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515316/ https://www.ncbi.nlm.nih.gov/pubmed/23284536 http://dx.doi.org/10.1107/S1600536812044248 |
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author | Kim, Tae Ho Moon, Suk-Hee Kim, Jineun Park, Ki-Min |
author_facet | Kim, Tae Ho Moon, Suk-Hee Kim, Jineun Park, Ki-Min |
author_sort | Kim, Tae Ho |
collection | PubMed |
description | In the title compound [systematic name: (3-chloro-2,6-dimethoxyphenyl)(ethoxyimino)methyl benzoate], C(18)H(18)ClNO(5), the phenyl and chlorodimethoxyphenyl rings are linked by the ethoxyiminomethyl benzoate system such that they are almost perpendicular to each other with the dihedral angle between them being 85.72 (9)°. In the crystal, C—H⋯O and C—H⋯Cl hydrogen bonds between the phenyl and chlorodimethoxyphenyl rings generate R (2) (2)(8) rings which link the molecules into zigzag chains along the b axis. Additional C—H⋯O contacts, together with weak intermolecular C—H⋯π interactions, further link the molecules into a three-dimensional network. |
format | Online Article Text |
id | pubmed-3515316 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35153162013-01-02 Benzoximate Kim, Tae Ho Moon, Suk-Hee Kim, Jineun Park, Ki-Min Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound [systematic name: (3-chloro-2,6-dimethoxyphenyl)(ethoxyimino)methyl benzoate], C(18)H(18)ClNO(5), the phenyl and chlorodimethoxyphenyl rings are linked by the ethoxyiminomethyl benzoate system such that they are almost perpendicular to each other with the dihedral angle between them being 85.72 (9)°. In the crystal, C—H⋯O and C—H⋯Cl hydrogen bonds between the phenyl and chlorodimethoxyphenyl rings generate R (2) (2)(8) rings which link the molecules into zigzag chains along the b axis. Additional C—H⋯O contacts, together with weak intermolecular C—H⋯π interactions, further link the molecules into a three-dimensional network. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515316/ /pubmed/23284536 http://dx.doi.org/10.1107/S1600536812044248 Text en © Kim et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kim, Tae Ho Moon, Suk-Hee Kim, Jineun Park, Ki-Min Benzoximate |
title | Benzoximate |
title_full | Benzoximate |
title_fullStr | Benzoximate |
title_full_unstemmed | Benzoximate |
title_short | Benzoximate |
title_sort | benzoximate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515316/ https://www.ncbi.nlm.nih.gov/pubmed/23284536 http://dx.doi.org/10.1107/S1600536812044248 |
work_keys_str_mv | AT kimtaeho benzoximate AT moonsukhee benzoximate AT kimjineun benzoximate AT parkkimin benzoximate |