(E)-1-(4-Nitro­benzyl­idene)-2,2-diphenyl­hydrazine

The asymmetric unit of the title compound, C(19)H(15)N(3)O(2), contains two mol­ecules, both of which show an E conformation of the imine bond. The dihedral angles between the phenyl rings in the phenyl­hydrazine groups are 86.09 (6) and 83.41 (5)° in the two mol­ecules. The 4-nitrobenzene rings sho...

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Autores principales: Mendoza, Angel, Meléndrez-Luevano, Ruth, Cabrera-Vivas, Blanca M., Acoltzi-X, Claudia, Flores-Alamo, Marcos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515317/
https://www.ncbi.nlm.nih.gov/pubmed/23284537
http://dx.doi.org/10.1107/S1600536812043681
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author Mendoza, Angel
Meléndrez-Luevano, Ruth
Cabrera-Vivas, Blanca M.
Acoltzi-X, Claudia
Flores-Alamo, Marcos
author_facet Mendoza, Angel
Meléndrez-Luevano, Ruth
Cabrera-Vivas, Blanca M.
Acoltzi-X, Claudia
Flores-Alamo, Marcos
author_sort Mendoza, Angel
collection PubMed
description The asymmetric unit of the title compound, C(19)H(15)N(3)O(2), contains two mol­ecules, both of which show an E conformation of the imine bond. The dihedral angles between the phenyl rings in the phenyl­hydrazine groups are 86.09 (6) and 83.41 (5)° in the two mol­ecules. The 4-nitrobenzene rings show torsion angles of 4.4 (2) and 10.9 (2)° from the two C=N—N planes. In the crystal, C—H⋯π inter­actions and C—H⋯O hydrogen bonds are observed growing along the a, b and c axes, resulting in a complex supramolecular array.
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spelling pubmed-35153172013-01-02 (E)-1-(4-Nitro­benzyl­idene)-2,2-diphenyl­hydrazine Mendoza, Angel Meléndrez-Luevano, Ruth Cabrera-Vivas, Blanca M. Acoltzi-X, Claudia Flores-Alamo, Marcos Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(19)H(15)N(3)O(2), contains two mol­ecules, both of which show an E conformation of the imine bond. The dihedral angles between the phenyl rings in the phenyl­hydrazine groups are 86.09 (6) and 83.41 (5)° in the two mol­ecules. The 4-nitrobenzene rings show torsion angles of 4.4 (2) and 10.9 (2)° from the two C=N—N planes. In the crystal, C—H⋯π inter­actions and C—H⋯O hydrogen bonds are observed growing along the a, b and c axes, resulting in a complex supramolecular array. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515317/ /pubmed/23284537 http://dx.doi.org/10.1107/S1600536812043681 Text en © Mendoza et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mendoza, Angel
Meléndrez-Luevano, Ruth
Cabrera-Vivas, Blanca M.
Acoltzi-X, Claudia
Flores-Alamo, Marcos
(E)-1-(4-Nitro­benzyl­idene)-2,2-diphenyl­hydrazine
title (E)-1-(4-Nitro­benzyl­idene)-2,2-diphenyl­hydrazine
title_full (E)-1-(4-Nitro­benzyl­idene)-2,2-diphenyl­hydrazine
title_fullStr (E)-1-(4-Nitro­benzyl­idene)-2,2-diphenyl­hydrazine
title_full_unstemmed (E)-1-(4-Nitro­benzyl­idene)-2,2-diphenyl­hydrazine
title_short (E)-1-(4-Nitro­benzyl­idene)-2,2-diphenyl­hydrazine
title_sort (e)-1-(4-nitro­benzyl­idene)-2,2-diphenyl­hydrazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515317/
https://www.ncbi.nlm.nih.gov/pubmed/23284537
http://dx.doi.org/10.1107/S1600536812043681
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