Cargando…
6,8-Dihydroxy-8a-methyl-3,5-dimethylidenedecahydronaphtho[2,3-b]furan-2(3H)-one
The title compound, C(15)H(20)O(4), is a eudesmanolide isolated from the Chinese medicinal plant Carpesium triste Maxim. The molecule contains three rings, viz. two fused six-membered rings in chair conformations and a five-membered ring in a flattened envelope conformation. In the crystal, two hy...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515328/ https://www.ncbi.nlm.nih.gov/pubmed/23284548 http://dx.doi.org/10.1107/S160053681204425X |
_version_ | 1782252161805058048 |
---|---|
author | Liu, Ting-ting Wu, Hai-Bo Wang, Wen-Shu |
author_facet | Liu, Ting-ting Wu, Hai-Bo Wang, Wen-Shu |
author_sort | Liu, Ting-ting |
collection | PubMed |
description | The title compound, C(15)H(20)O(4), is a eudesmanolide isolated from the Chinese medicinal plant Carpesium triste Maxim. The molecule contains three rings, viz. two fused six-membered rings in chair conformations and a five-membered ring in a flattened envelope conformation. In the crystal, two hydroxy groups are involved in the formation of intra- and intermolecular O—H⋯O hydrogen bonds. The H atoms in these groups are split, with site-occupation factors of 0.5. The intermolecular hydrogen bonds link molecules into chains propagating in [010]. |
format | Online Article Text |
id | pubmed-3515328 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35153282013-01-02 6,8-Dihydroxy-8a-methyl-3,5-dimethylidenedecahydronaphtho[2,3-b]furan-2(3H)-one Liu, Ting-ting Wu, Hai-Bo Wang, Wen-Shu Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(20)O(4), is a eudesmanolide isolated from the Chinese medicinal plant Carpesium triste Maxim. The molecule contains three rings, viz. two fused six-membered rings in chair conformations and a five-membered ring in a flattened envelope conformation. In the crystal, two hydroxy groups are involved in the formation of intra- and intermolecular O—H⋯O hydrogen bonds. The H atoms in these groups are split, with site-occupation factors of 0.5. The intermolecular hydrogen bonds link molecules into chains propagating in [010]. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515328/ /pubmed/23284548 http://dx.doi.org/10.1107/S160053681204425X Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Liu, Ting-ting Wu, Hai-Bo Wang, Wen-Shu 6,8-Dihydroxy-8a-methyl-3,5-dimethylidenedecahydronaphtho[2,3-b]furan-2(3H)-one |
title | 6,8-Dihydroxy-8a-methyl-3,5-dimethylidenedecahydronaphtho[2,3-b]furan-2(3H)-one |
title_full | 6,8-Dihydroxy-8a-methyl-3,5-dimethylidenedecahydronaphtho[2,3-b]furan-2(3H)-one |
title_fullStr | 6,8-Dihydroxy-8a-methyl-3,5-dimethylidenedecahydronaphtho[2,3-b]furan-2(3H)-one |
title_full_unstemmed | 6,8-Dihydroxy-8a-methyl-3,5-dimethylidenedecahydronaphtho[2,3-b]furan-2(3H)-one |
title_short | 6,8-Dihydroxy-8a-methyl-3,5-dimethylidenedecahydronaphtho[2,3-b]furan-2(3H)-one |
title_sort | 6,8-dihydroxy-8a-methyl-3,5-dimethylidenedecahydronaphtho[2,3-b]furan-2(3h)-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515328/ https://www.ncbi.nlm.nih.gov/pubmed/23284548 http://dx.doi.org/10.1107/S160053681204425X |
work_keys_str_mv | AT liutingting 68dihydroxy8amethyl35dimethylidenedecahydronaphtho23bfuran23hone AT wuhaibo 68dihydroxy8amethyl35dimethylidenedecahydronaphtho23bfuran23hone AT wangwenshu 68dihydroxy8amethyl35dimethylidenedecahydronaphtho23bfuran23hone |