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6,8-Dihy­droxy-8a-methyl-3,5-dimethyl­idenedeca­hydro­naphtho­[2,3-b]furan-2(3H)-one

The title compound, C(15)H(20)O(4), is a eudesmanolide isolated from the Chinese medicinal plant Carpesium tris­te Maxim. The mol­ecule contains three rings, viz. two fused six-membered rings in chair conformations and a five-membered ring in a flattened envelope conformation. In the crystal, two hy...

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Detalles Bibliográficos
Autores principales: Liu, Ting-ting, Wu, Hai-Bo, Wang, Wen-Shu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515328/
https://www.ncbi.nlm.nih.gov/pubmed/23284548
http://dx.doi.org/10.1107/S160053681204425X
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author Liu, Ting-ting
Wu, Hai-Bo
Wang, Wen-Shu
author_facet Liu, Ting-ting
Wu, Hai-Bo
Wang, Wen-Shu
author_sort Liu, Ting-ting
collection PubMed
description The title compound, C(15)H(20)O(4), is a eudesmanolide isolated from the Chinese medicinal plant Carpesium tris­te Maxim. The mol­ecule contains three rings, viz. two fused six-membered rings in chair conformations and a five-membered ring in a flattened envelope conformation. In the crystal, two hy­droxy groups are involved in the formation of intra- and inter­molecular O—H⋯O hydrogen bonds. The H atoms in these groups are split, with site-occupation factors of 0.5. The inter­molecular hydrogen bonds link mol­ecules into chains propagating in [010].
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spelling pubmed-35153282013-01-02 6,8-Dihy­droxy-8a-methyl-3,5-dimethyl­idenedeca­hydro­naphtho­[2,3-b]furan-2(3H)-one Liu, Ting-ting Wu, Hai-Bo Wang, Wen-Shu Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(20)O(4), is a eudesmanolide isolated from the Chinese medicinal plant Carpesium tris­te Maxim. The mol­ecule contains three rings, viz. two fused six-membered rings in chair conformations and a five-membered ring in a flattened envelope conformation. In the crystal, two hy­droxy groups are involved in the formation of intra- and inter­molecular O—H⋯O hydrogen bonds. The H atoms in these groups are split, with site-occupation factors of 0.5. The inter­molecular hydrogen bonds link mol­ecules into chains propagating in [010]. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515328/ /pubmed/23284548 http://dx.doi.org/10.1107/S160053681204425X Text en © Liu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Ting-ting
Wu, Hai-Bo
Wang, Wen-Shu
6,8-Dihy­droxy-8a-methyl-3,5-dimethyl­idenedeca­hydro­naphtho­[2,3-b]furan-2(3H)-one
title 6,8-Dihy­droxy-8a-methyl-3,5-dimethyl­idenedeca­hydro­naphtho­[2,3-b]furan-2(3H)-one
title_full 6,8-Dihy­droxy-8a-methyl-3,5-dimethyl­idenedeca­hydro­naphtho­[2,3-b]furan-2(3H)-one
title_fullStr 6,8-Dihy­droxy-8a-methyl-3,5-dimethyl­idenedeca­hydro­naphtho­[2,3-b]furan-2(3H)-one
title_full_unstemmed 6,8-Dihy­droxy-8a-methyl-3,5-dimethyl­idenedeca­hydro­naphtho­[2,3-b]furan-2(3H)-one
title_short 6,8-Dihy­droxy-8a-methyl-3,5-dimethyl­idenedeca­hydro­naphtho­[2,3-b]furan-2(3H)-one
title_sort 6,8-dihy­droxy-8a-methyl-3,5-dimethyl­idenedeca­hydro­naphtho­[2,3-b]furan-2(3h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515328/
https://www.ncbi.nlm.nih.gov/pubmed/23284548
http://dx.doi.org/10.1107/S160053681204425X
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