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Piperidine-1-carboximidamide
In the title compound, C(6)H(13)N(3), the C=N and C—N bond lengths in the CN(3) unit are 1.3090 (17), and 1.3640 (17) (C–NH(2)) and 1.3773 (16) Å, indicating double- and single-bond character, respectively. The N—C—N angles are 116.82 (12), 119.08 (11) and 124.09 (11)°, showing a deviation of the CN...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515330/ https://www.ncbi.nlm.nih.gov/pubmed/23284550 http://dx.doi.org/10.1107/S1600536812044467 |
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author | Tiritiris, Ioannis |
author_facet | Tiritiris, Ioannis |
author_sort | Tiritiris, Ioannis |
collection | PubMed |
description | In the title compound, C(6)H(13)N(3), the C=N and C—N bond lengths in the CN(3) unit are 1.3090 (17), and 1.3640 (17) (C–NH(2)) and 1.3773 (16) Å, indicating double- and single-bond character, respectively. The N—C—N angles are 116.82 (12), 119.08 (11) and 124.09 (11)°, showing a deviation of the CN(3) plane from an ideal trigonal–planar geometry. The piperidine ring is in a chair conformation. In the crystal, molecules are linked by N—H⋯N hydrogen bonds, forming a two-dimensional network along the ac plane. |
format | Online Article Text |
id | pubmed-3515330 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35153302013-01-02 Piperidine-1-carboximidamide Tiritiris, Ioannis Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(13)N(3), the C=N and C—N bond lengths in the CN(3) unit are 1.3090 (17), and 1.3640 (17) (C–NH(2)) and 1.3773 (16) Å, indicating double- and single-bond character, respectively. The N—C—N angles are 116.82 (12), 119.08 (11) and 124.09 (11)°, showing a deviation of the CN(3) plane from an ideal trigonal–planar geometry. The piperidine ring is in a chair conformation. In the crystal, molecules are linked by N—H⋯N hydrogen bonds, forming a two-dimensional network along the ac plane. International Union of Crystallography 2012-10-31 /pmc/articles/PMC3515330/ /pubmed/23284550 http://dx.doi.org/10.1107/S1600536812044467 Text en © Ioannis Tiritiris 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tiritiris, Ioannis Piperidine-1-carboximidamide |
title | Piperidine-1-carboximidamide |
title_full | Piperidine-1-carboximidamide |
title_fullStr | Piperidine-1-carboximidamide |
title_full_unstemmed | Piperidine-1-carboximidamide |
title_short | Piperidine-1-carboximidamide |
title_sort | piperidine-1-carboximidamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3515330/ https://www.ncbi.nlm.nih.gov/pubmed/23284550 http://dx.doi.org/10.1107/S1600536812044467 |
work_keys_str_mv | AT tiritirisioannis piperidine1carboximidamide |