Unusual C=C Bond Isomerization of an α,β-Unsaturated γ-Butyrolactone Catalysed by Flavoproteins from the Old Yellow Enzyme Family

An unexpected, redox-neutral C=C bond isomerization of a γ-butyrolactone bearing an exo-methylene unit to the thermodynamically more favoured endo isomer (k(cat) = 0.076 s(−1)) catalysed by flavoproteins from the Old Yellow Enzyme family was discovered. Theoretical calculations and kinetic data supp...

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Detalles Bibliográficos
Autores principales: Durchschein, Katharina, Wallner, Silvia, Macheroux, Peter, Zangger, Klaus, Fabian, Walter M F, Faber, Kurt
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2012
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3533789/
https://www.ncbi.nlm.nih.gov/pubmed/23024004
http://dx.doi.org/10.1002/cbic.201200475

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3533789/
https://www.ncbi.nlm.nih.gov/pubmed/23024004
http://dx.doi.org/10.1002/cbic.201200475

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