Control Self-Assembly of Hydrazide-Based Cyclic Hexamers: In or Out

By moving the alkoxy group on the spacer from position 5 to position 4 to add another protocol for the algorithm for intermolecular and intramolecular hydrogen bonding interactions, highly regioselectivity of noncovalent synthesis of the hydrazide-based cyclic hexamers was achieved: one out of thirt...

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Detalles Bibliográficos
Autores principales: Yang, Yong, Huang, Fei, Chen, Chuan-Feng, Xia, Min, Cai, Qingyun, Qian, Fang-Jun, Xiang, Junfeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3544009/
https://www.ncbi.nlm.nih.gov/pubmed/23320140
http://dx.doi.org/10.1038/srep01059
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author Yang, Yong
Huang, Fei
Chen, Chuan-Feng
Xia, Min
Cai, Qingyun
Qian, Fang-Jun
Xiang, Junfeng
author_facet Yang, Yong
Huang, Fei
Chen, Chuan-Feng
Xia, Min
Cai, Qingyun
Qian, Fang-Jun
Xiang, Junfeng
author_sort Yang, Yong
collection PubMed
description By moving the alkoxy group on the spacer from position 5 to position 4 to add another protocol for the algorithm for intermolecular and intramolecular hydrogen bonding interactions, highly regioselectivity of noncovalent synthesis of the hydrazide-based cyclic hexamers was achieved: one out of thirteen possible isomeric cyclic hexamers selectively formed and thus precise control of the two hydrazide units in the cyclic hexamers (in or out) was accomplished.
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spelling pubmed-35440092013-01-14 Control Self-Assembly of Hydrazide-Based Cyclic Hexamers: In or Out Yang, Yong Huang, Fei Chen, Chuan-Feng Xia, Min Cai, Qingyun Qian, Fang-Jun Xiang, Junfeng Sci Rep Article By moving the alkoxy group on the spacer from position 5 to position 4 to add another protocol for the algorithm for intermolecular and intramolecular hydrogen bonding interactions, highly regioselectivity of noncovalent synthesis of the hydrazide-based cyclic hexamers was achieved: one out of thirteen possible isomeric cyclic hexamers selectively formed and thus precise control of the two hydrazide units in the cyclic hexamers (in or out) was accomplished. Nature Publishing Group 2013-01-14 /pmc/articles/PMC3544009/ /pubmed/23320140 http://dx.doi.org/10.1038/srep01059 Text en Copyright © 2013, Macmillan Publishers Limited. All rights reserved http://creativecommons.org/licenses/by-nc-nd/3.0/ This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported License. To view a copy of this license, visit http://creativecommons.org/licenses/by-nc-nd/3.0/
spellingShingle Article
Yang, Yong
Huang, Fei
Chen, Chuan-Feng
Xia, Min
Cai, Qingyun
Qian, Fang-Jun
Xiang, Junfeng
Control Self-Assembly of Hydrazide-Based Cyclic Hexamers: In or Out
title Control Self-Assembly of Hydrazide-Based Cyclic Hexamers: In or Out
title_full Control Self-Assembly of Hydrazide-Based Cyclic Hexamers: In or Out
title_fullStr Control Self-Assembly of Hydrazide-Based Cyclic Hexamers: In or Out
title_full_unstemmed Control Self-Assembly of Hydrazide-Based Cyclic Hexamers: In or Out
title_short Control Self-Assembly of Hydrazide-Based Cyclic Hexamers: In or Out
title_sort control self-assembly of hydrazide-based cyclic hexamers: in or out
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3544009/
https://www.ncbi.nlm.nih.gov/pubmed/23320140
http://dx.doi.org/10.1038/srep01059
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