Influence of cyclodextrin on the solubility and the polymerization of (meth)acrylated Triton(®) X-100

Triton(®) X-100 (poly(ethylene glycol) tert-octylphenyl ether) was (meth)acrylated and polymerized in the absence and presence of randomly methylated β-cyclodextrin (RAMEB-CD). Triton(®)-polymers that were polymerized with RAMEB-CD in water were compared with polymers that were synthesized in organi...

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Detalles Bibliográficos
Autores principales: Kemnitz, Melanie, Ritter, Helmut
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2012
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3555431/
https://www.ncbi.nlm.nih.gov/pubmed/23378858
http://dx.doi.org/10.3762/bjoc.8.245
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author Kemnitz, Melanie
Ritter, Helmut
author_facet Kemnitz, Melanie
Ritter, Helmut
author_sort Kemnitz, Melanie
collection PubMed
description Triton(®) X-100 (poly(ethylene glycol) tert-octylphenyl ether) was (meth)acrylated and polymerized in the absence and presence of randomly methylated β-cyclodextrin (RAMEB-CD). Triton(®)-polymers that were polymerized with RAMEB-CD in water were compared with polymers that were synthesized in organic solvents after the addition of RAMEB-CD. The polymers were characterized by (1)H NMR and FTIR spectroscopy, matrix-assisted laser desorption ionization mass spectrometry (MALDI-TOF MS), dynamic light scattering (DLS), gel-permeation chromatography (GPC) and turbidity measurements. Additionally, the viscosity change of the methacrylic homopolymer with RAMEB-CD was evaluated.
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spelling pubmed-35554312013-02-01 Influence of cyclodextrin on the solubility and the polymerization of (meth)acrylated Triton(®) X-100 Kemnitz, Melanie Ritter, Helmut Beilstein J Org Chem Full Research Paper Triton(®) X-100 (poly(ethylene glycol) tert-octylphenyl ether) was (meth)acrylated and polymerized in the absence and presence of randomly methylated β-cyclodextrin (RAMEB-CD). Triton(®)-polymers that were polymerized with RAMEB-CD in water were compared with polymers that were synthesized in organic solvents after the addition of RAMEB-CD. The polymers were characterized by (1)H NMR and FTIR spectroscopy, matrix-assisted laser desorption ionization mass spectrometry (MALDI-TOF MS), dynamic light scattering (DLS), gel-permeation chromatography (GPC) and turbidity measurements. Additionally, the viscosity change of the methacrylic homopolymer with RAMEB-CD was evaluated. Beilstein-Institut 2012-12-13 /pmc/articles/PMC3555431/ /pubmed/23378858 http://dx.doi.org/10.3762/bjoc.8.245 Text en Copyright © 2012, Kemnitz and Ritter https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Kemnitz, Melanie
Ritter, Helmut
Influence of cyclodextrin on the solubility and the polymerization of (meth)acrylated Triton(®) X-100
title Influence of cyclodextrin on the solubility and the polymerization of (meth)acrylated Triton(®) X-100
title_full Influence of cyclodextrin on the solubility and the polymerization of (meth)acrylated Triton(®) X-100
title_fullStr Influence of cyclodextrin on the solubility and the polymerization of (meth)acrylated Triton(®) X-100
title_full_unstemmed Influence of cyclodextrin on the solubility and the polymerization of (meth)acrylated Triton(®) X-100
title_short Influence of cyclodextrin on the solubility and the polymerization of (meth)acrylated Triton(®) X-100
title_sort influence of cyclodextrin on the solubility and the polymerization of (meth)acrylated triton(®) x-100
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3555431/
https://www.ncbi.nlm.nih.gov/pubmed/23378858
http://dx.doi.org/10.3762/bjoc.8.245
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