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Mechanistic Investigations and Substrate Scope Evaluation of Ruthenium-Catalyzed Direct sp(3) Arylation of Benzylic Positions Directed by 3-Substituted Pyridines
[Image: see text] A highly efficient direct arylation process of benzylic amines with arylboronates was developed that employs Ru catalysis. The arylation takes place with greatest efficiency at the benzylic sp(3) carbon. If the distance to the activating aryl ring is increased, arylation is still p...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2012
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3557922/ https://www.ncbi.nlm.nih.gov/pubmed/23236951 http://dx.doi.org/10.1021/jo302547q |