Cross-trienamines in Asymmetric Organocatalysis

[Image: see text] Cross-conjugated trienamines are introduced as a new concept in asymmetric organocatalysis. These intermediates are applied in highly enantioselective Diels–Alder and addition reactions, providing functionalized bicyclo[2.2.2]octane compounds and γ′-addition products, respectively....

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Detalles Bibliográficos
Autores principales: Halskov, Kim Søholm, Johansen, Tore Kiilerich, Davis, Rebecca L., Steurer, Marianne, Jensen, Frank, Jørgensen, Karl Anker
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2012
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3557926/
https://www.ncbi.nlm.nih.gov/pubmed/22835208
http://dx.doi.org/10.1021/ja3068269
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author Halskov, Kim Søholm
Johansen, Tore Kiilerich
Davis, Rebecca L.
Steurer, Marianne
Jensen, Frank
Jørgensen, Karl Anker
author_facet Halskov, Kim Søholm
Johansen, Tore Kiilerich
Davis, Rebecca L.
Steurer, Marianne
Jensen, Frank
Jørgensen, Karl Anker
author_sort Halskov, Kim Søholm
collection PubMed
description [Image: see text] Cross-conjugated trienamines are introduced as a new concept in asymmetric organocatalysis. These intermediates are applied in highly enantioselective Diels–Alder and addition reactions, providing functionalized bicyclo[2.2.2]octane compounds and γ′-addition products, respectively. The nature of the transformations and the intermediates involved are investigated by computational calculations and NMR analysis.
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spelling pubmed-35579262013-01-31 Cross-trienamines in Asymmetric Organocatalysis Halskov, Kim Søholm Johansen, Tore Kiilerich Davis, Rebecca L. Steurer, Marianne Jensen, Frank Jørgensen, Karl Anker J Am Chem Soc [Image: see text] Cross-conjugated trienamines are introduced as a new concept in asymmetric organocatalysis. These intermediates are applied in highly enantioselective Diels–Alder and addition reactions, providing functionalized bicyclo[2.2.2]octane compounds and γ′-addition products, respectively. The nature of the transformations and the intermediates involved are investigated by computational calculations and NMR analysis. American Chemical Society 2012-07-26 2012-08-08 /pmc/articles/PMC3557926/ /pubmed/22835208 http://dx.doi.org/10.1021/ja3068269 Text en Copyright © 2012 American Chemical Society Terms of Use (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html)
spellingShingle Halskov, Kim Søholm
Johansen, Tore Kiilerich
Davis, Rebecca L.
Steurer, Marianne
Jensen, Frank
Jørgensen, Karl Anker
Cross-trienamines in Asymmetric Organocatalysis
title Cross-trienamines in Asymmetric Organocatalysis
title_full Cross-trienamines in Asymmetric Organocatalysis
title_fullStr Cross-trienamines in Asymmetric Organocatalysis
title_full_unstemmed Cross-trienamines in Asymmetric Organocatalysis
title_short Cross-trienamines in Asymmetric Organocatalysis
title_sort cross-trienamines in asymmetric organocatalysis
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3557926/
https://www.ncbi.nlm.nih.gov/pubmed/22835208
http://dx.doi.org/10.1021/ja3068269
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