Synthesis and Characterization of Redox-Active Charge-Transfer Complexes with 2,3,5,6-Tetracyanopyridine (TCNPy) for the Photogeneration of Pyridinium Radicals

The heteroaromatic polynitrile compound tetracyanopyridine (TCNPy) is introduced as a new electron acceptor for the formation of deeply colored charge-transfer complexes. In MeCN, TCNPy is characterized by a quasireversible one-electron-reduction process at −0.51 V (versus SCE). The tetracyanopyridi...

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Detalles Bibliográficos
Autores principales: Wöß, Eva, Monkowius, Uwe, Knör, Günther
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2013
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3564414/
https://www.ncbi.nlm.nih.gov/pubmed/23233370
http://dx.doi.org/10.1002/chem.201201915

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3564414/
https://www.ncbi.nlm.nih.gov/pubmed/23233370
http://dx.doi.org/10.1002/chem.201201915

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