Removal of benzylidene acetal and benzyl ether in carbohydrate derivatives using triethylsilane and Pd/C

Clean deprotection of carbohydrate derivatives containing benzylidene acetals and benzyl ethers was achieved under catalytic transfer hydrogenation conditions by using a combination of triethylsilane and 10% Pd/C in CH(3)OH at room temperature. A variety of carbohydrate diol derivatives were prepare...

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Detalles Bibliográficos
Autores principales: Santra, Abhishek, Ghosh, Tamashree, Misra, Anup Kumar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3566760/
https://www.ncbi.nlm.nih.gov/pubmed/23400301
http://dx.doi.org/10.3762/bjoc.9.9
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author Santra, Abhishek
Ghosh, Tamashree
Misra, Anup Kumar
author_facet Santra, Abhishek
Ghosh, Tamashree
Misra, Anup Kumar
author_sort Santra, Abhishek
collection PubMed
description Clean deprotection of carbohydrate derivatives containing benzylidene acetals and benzyl ethers was achieved under catalytic transfer hydrogenation conditions by using a combination of triethylsilane and 10% Pd/C in CH(3)OH at room temperature. A variety of carbohydrate diol derivatives were prepared from their benzylidene derivatives in excellent yield.
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spelling pubmed-35667602013-02-11 Removal of benzylidene acetal and benzyl ether in carbohydrate derivatives using triethylsilane and Pd/C Santra, Abhishek Ghosh, Tamashree Misra, Anup Kumar Beilstein J Org Chem Full Research Paper Clean deprotection of carbohydrate derivatives containing benzylidene acetals and benzyl ethers was achieved under catalytic transfer hydrogenation conditions by using a combination of triethylsilane and 10% Pd/C in CH(3)OH at room temperature. A variety of carbohydrate diol derivatives were prepared from their benzylidene derivatives in excellent yield. Beilstein-Institut 2013-01-14 /pmc/articles/PMC3566760/ /pubmed/23400301 http://dx.doi.org/10.3762/bjoc.9.9 Text en Copyright © 2013, Santra et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Santra, Abhishek
Ghosh, Tamashree
Misra, Anup Kumar
Removal of benzylidene acetal and benzyl ether in carbohydrate derivatives using triethylsilane and Pd/C
title Removal of benzylidene acetal and benzyl ether in carbohydrate derivatives using triethylsilane and Pd/C
title_full Removal of benzylidene acetal and benzyl ether in carbohydrate derivatives using triethylsilane and Pd/C
title_fullStr Removal of benzylidene acetal and benzyl ether in carbohydrate derivatives using triethylsilane and Pd/C
title_full_unstemmed Removal of benzylidene acetal and benzyl ether in carbohydrate derivatives using triethylsilane and Pd/C
title_short Removal of benzylidene acetal and benzyl ether in carbohydrate derivatives using triethylsilane and Pd/C
title_sort removal of benzylidene acetal and benzyl ether in carbohydrate derivatives using triethylsilane and pd/c
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3566760/
https://www.ncbi.nlm.nih.gov/pubmed/23400301
http://dx.doi.org/10.3762/bjoc.9.9
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AT ghoshtamashree removalofbenzylideneacetalandbenzyletherincarbohydratederivativesusingtriethylsilaneandpdc
AT misraanupkumar removalofbenzylideneacetalandbenzyletherincarbohydratederivativesusingtriethylsilaneandpdc

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