The defect scheelite-type lanthanum(III) ortho-oxidomolybdate(VI) La(0.667)[MoO(4)]

In scheelite-type La(0.667)[MoO(4)], one crystallographically unique position with site symmetry -4.. and an occupancy of 2/3 is found for the La(3+) cation. The cation is surrounded by eight O atoms in the shape of a trigonal dodeca­hedron. The structure also contains one [MoO(4)](2−) anion (site s...

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Detalles Bibliográficos
Autores principales: Schustereit, Tanja, Schleid, Thomas, Hartenbach, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569171/
https://www.ncbi.nlm.nih.gov/pubmed/23424397
http://dx.doi.org/10.1107/S1600536813000731
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author Schustereit, Tanja
Schleid, Thomas
Hartenbach, Ingo
author_facet Schustereit, Tanja
Schleid, Thomas
Hartenbach, Ingo
author_sort Schustereit, Tanja
collection PubMed
description In scheelite-type La(0.667)[MoO(4)], one crystallographically unique position with site symmetry -4.. and an occupancy of 2/3 is found for the La(3+) cation. The cation is surrounded by eight O atoms in the shape of a trigonal dodeca­hedron. The structure also contains one [MoO(4)](2−) anion (site symmetry -4..), which is surrounded by eight vertex-attached La(3+) cations. The polyhedra around the La(3+) cations are inter­connected via common edges, building up a three-dimensional network, in the tetra­hedral voids of which the Mo(6+) cations reside.
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spelling pubmed-35691712013-02-19 The defect scheelite-type lanthanum(III) ortho-oxidomolybdate(VI) La(0.667)[MoO(4)] Schustereit, Tanja Schleid, Thomas Hartenbach, Ingo Acta Crystallogr Sect E Struct Rep Online Inorganic Papers In scheelite-type La(0.667)[MoO(4)], one crystallographically unique position with site symmetry -4.. and an occupancy of 2/3 is found for the La(3+) cation. The cation is surrounded by eight O atoms in the shape of a trigonal dodeca­hedron. The structure also contains one [MoO(4)](2−) anion (site symmetry -4..), which is surrounded by eight vertex-attached La(3+) cations. The polyhedra around the La(3+) cations are inter­connected via common edges, building up a three-dimensional network, in the tetra­hedral voids of which the Mo(6+) cations reside. International Union of Crystallography 2013-01-16 /pmc/articles/PMC3569171/ /pubmed/23424397 http://dx.doi.org/10.1107/S1600536813000731 Text en © Schustereit et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Schustereit, Tanja
Schleid, Thomas
Hartenbach, Ingo
The defect scheelite-type lanthanum(III) ortho-oxidomolybdate(VI) La(0.667)[MoO(4)]
title The defect scheelite-type lanthanum(III) ortho-oxidomolybdate(VI) La(0.667)[MoO(4)]
title_full The defect scheelite-type lanthanum(III) ortho-oxidomolybdate(VI) La(0.667)[MoO(4)]
title_fullStr The defect scheelite-type lanthanum(III) ortho-oxidomolybdate(VI) La(0.667)[MoO(4)]
title_full_unstemmed The defect scheelite-type lanthanum(III) ortho-oxidomolybdate(VI) La(0.667)[MoO(4)]
title_short The defect scheelite-type lanthanum(III) ortho-oxidomolybdate(VI) La(0.667)[MoO(4)]
title_sort defect scheelite-type lanthanum(iii) ortho-oxidomolybdate(vi) la(0.667)[moo(4)]
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569171/
https://www.ncbi.nlm.nih.gov/pubmed/23424397
http://dx.doi.org/10.1107/S1600536813000731
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