Bis(diethyl­amido-κN)(diethyl­amine-κN)bis­(2,6-diisopropyl­phenyl­amido-κN)zirconium(IV)

In the title compound, [Zr(C(12)H(18)N)(2)(C(4)H(10)N)(2)(C(4)H(11)N)] or [Zr(HNC(6)H(3) (i)Pr(2))(2)(NEt(2))(2)(HNEt(2))], which was obtained by the reaction of Zr(NEt)(4) with (i)Pr(2)C(6)H(3)NH(2), the Zr(IV) atom is in a trigonal–bipiramidal geometry in which the N atoms from two (i)Pr(2)C(6)H(3...

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Detalles Bibliográficos
Autores principales: Zauliczny, Mateusz, Grubba, Rafał, Ponikiewski, Łukasz, Pikies, Jerzy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569177/
https://www.ncbi.nlm.nih.gov/pubmed/23424421
http://dx.doi.org/10.1107/S160053681205115X
Descripción
Sumario:In the title compound, [Zr(C(12)H(18)N)(2)(C(4)H(10)N)(2)(C(4)H(11)N)] or [Zr(HNC(6)H(3) (i)Pr(2))(2)(NEt(2))(2)(HNEt(2))], which was obtained by the reaction of Zr(NEt)(4) with (i)Pr(2)C(6)H(3)NH(2), the Zr(IV) atom is in a trigonal–bipiramidal geometry in which the N atoms from two (i)Pr(2)C(6)H(3)NH and one NEt(2) ligand occupy the equatorial positions, and the N atoms of an NEt(2) and an Et(2)NH ligand occupy the apical positions. An intra­molecular N—H⋯N contact occurs. There are two independent molecules in the asymmetric unit.

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