Bis(diethyl­amido-κN)(diethyl­amine-κN)bis­(2,6-diisopropyl­phenyl­amido-κN)zirconium(IV)

In the title compound, [Zr(C(12)H(18)N)(2)(C(4)H(10)N)(2)(C(4)H(11)N)] or [Zr(HNC(6)H(3) (i)Pr(2))(2)(NEt(2))(2)(HNEt(2))], which was obtained by the reaction of Zr(NEt)(4) with (i)Pr(2)C(6)H(3)NH(2), the Zr(IV) atom is in a trigonal–bipiramidal geometry in which the N atoms from two (i)Pr(2)C(6)H(3...

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Autores principales: Zauliczny, Mateusz, Grubba, Rafał, Ponikiewski, Łukasz, Pikies, Jerzy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569177/
https://www.ncbi.nlm.nih.gov/pubmed/23424421
http://dx.doi.org/10.1107/S160053681205115X
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author Zauliczny, Mateusz
Grubba, Rafał
Ponikiewski, Łukasz
Pikies, Jerzy
author_facet Zauliczny, Mateusz
Grubba, Rafał
Ponikiewski, Łukasz
Pikies, Jerzy
author_sort Zauliczny, Mateusz
collection PubMed
description In the title compound, [Zr(C(12)H(18)N)(2)(C(4)H(10)N)(2)(C(4)H(11)N)] or [Zr(HNC(6)H(3) (i)Pr(2))(2)(NEt(2))(2)(HNEt(2))], which was obtained by the reaction of Zr(NEt)(4) with (i)Pr(2)C(6)H(3)NH(2), the Zr(IV) atom is in a trigonal–bipiramidal geometry in which the N atoms from two (i)Pr(2)C(6)H(3)NH and one NEt(2) ligand occupy the equatorial positions, and the N atoms of an NEt(2) and an Et(2)NH ligand occupy the apical positions. An intra­molecular N—H⋯N contact occurs. There are two independent molecules in the asymmetric unit.
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spelling pubmed-35691772013-02-19 Bis(diethyl­amido-κN)(diethyl­amine-κN)bis­(2,6-diisopropyl­phenyl­amido-κN)zirconium(IV) Zauliczny, Mateusz Grubba, Rafał Ponikiewski, Łukasz Pikies, Jerzy Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zr(C(12)H(18)N)(2)(C(4)H(10)N)(2)(C(4)H(11)N)] or [Zr(HNC(6)H(3) (i)Pr(2))(2)(NEt(2))(2)(HNEt(2))], which was obtained by the reaction of Zr(NEt)(4) with (i)Pr(2)C(6)H(3)NH(2), the Zr(IV) atom is in a trigonal–bipiramidal geometry in which the N atoms from two (i)Pr(2)C(6)H(3)NH and one NEt(2) ligand occupy the equatorial positions, and the N atoms of an NEt(2) and an Et(2)NH ligand occupy the apical positions. An intra­molecular N—H⋯N contact occurs. There are two independent molecules in the asymmetric unit. International Union of Crystallography 2013-01-04 /pmc/articles/PMC3569177/ /pubmed/23424421 http://dx.doi.org/10.1107/S160053681205115X Text en © Zauliczny et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zauliczny, Mateusz
Grubba, Rafał
Ponikiewski, Łukasz
Pikies, Jerzy
Bis(diethyl­amido-κN)(diethyl­amine-κN)bis­(2,6-diisopropyl­phenyl­amido-κN)zirconium(IV)
title Bis(diethyl­amido-κN)(diethyl­amine-κN)bis­(2,6-diisopropyl­phenyl­amido-κN)zirconium(IV)
title_full Bis(diethyl­amido-κN)(diethyl­amine-κN)bis­(2,6-diisopropyl­phenyl­amido-κN)zirconium(IV)
title_fullStr Bis(diethyl­amido-κN)(diethyl­amine-κN)bis­(2,6-diisopropyl­phenyl­amido-κN)zirconium(IV)
title_full_unstemmed Bis(diethyl­amido-κN)(diethyl­amine-κN)bis­(2,6-diisopropyl­phenyl­amido-κN)zirconium(IV)
title_short Bis(diethyl­amido-κN)(diethyl­amine-κN)bis­(2,6-diisopropyl­phenyl­amido-κN)zirconium(IV)
title_sort bis(diethyl­amido-κn)(diethyl­amine-κn)bis­(2,6-diisopropyl­phenyl­amido-κn)zirconium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569177/
https://www.ncbi.nlm.nih.gov/pubmed/23424421
http://dx.doi.org/10.1107/S160053681205115X
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