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cis-Bis(1,10-phenanthroline-κ(2) N,N′)bis(pyridin-4-amine-κN (1))ruthenium(II) bis(hexafluoridophosphate)
In the title complex, [Ru(C(12)H(8)N(2))(2)(C(5)H(6)N(2))(2)](PF(6))(2), the Ru(II) atom is bonded to two α-diimine ligands, viz. 1,10-phenanthroline (phen), in a cis configuration, in addition with with two 4-aminopyridine (4Apy) ligands, resulting in a distorted octahedral coordination geometry....
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569179/ https://www.ncbi.nlm.nih.gov/pubmed/23424423 http://dx.doi.org/10.1107/S1600536812051999 |
| _version_ | 1782258845218766848 |
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| author | Camilo, Mariana R. Martins, Felipe T. Malta, Valéria R. S. Ellena, Javier Carlos, Rose M. |
| author_facet | Camilo, Mariana R. Martins, Felipe T. Malta, Valéria R. S. Ellena, Javier Carlos, Rose M. |
| author_sort | Camilo, Mariana R. |
| collection | PubMed |
| description | In the title complex, [Ru(C(12)H(8)N(2))(2)(C(5)H(6)N(2))(2)](PF(6))(2), the Ru(II) atom is bonded to two α-diimine ligands, viz. 1,10-phenanthroline (phen), in a cis configuration, in addition with with two 4-aminopyridine (4Apy) ligands, resulting in a distorted octahedral coordination geometry. N—H⋯F hydrogen-bonding interactions play an important role in the crystal assembly: 2(1)-screw-axis-related complex molecules and PF(6) (−) counter-ions alternate in helical chains formed along the a axis by means of these contacts. N—H⋯π contacts (H⋯centroid = 3.45 Å) are responsible for cross-linking between the helical chains along [001]. |
| format | Online Article Text |
| id | pubmed-3569179 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-35691792013-02-19 cis-Bis(1,10-phenanthroline-κ(2) N,N′)bis(pyridin-4-amine-κN (1))ruthenium(II) bis(hexafluoridophosphate) Camilo, Mariana R. Martins, Felipe T. Malta, Valéria R. S. Ellena, Javier Carlos, Rose M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ru(C(12)H(8)N(2))(2)(C(5)H(6)N(2))(2)](PF(6))(2), the Ru(II) atom is bonded to two α-diimine ligands, viz. 1,10-phenanthroline (phen), in a cis configuration, in addition with with two 4-aminopyridine (4Apy) ligands, resulting in a distorted octahedral coordination geometry. N—H⋯F hydrogen-bonding interactions play an important role in the crystal assembly: 2(1)-screw-axis-related complex molecules and PF(6) (−) counter-ions alternate in helical chains formed along the a axis by means of these contacts. N—H⋯π contacts (H⋯centroid = 3.45 Å) are responsible for cross-linking between the helical chains along [001]. International Union of Crystallography 2013-01-09 /pmc/articles/PMC3569179/ /pubmed/23424423 http://dx.doi.org/10.1107/S1600536812051999 Text en © Camilo et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Camilo, Mariana R. Martins, Felipe T. Malta, Valéria R. S. Ellena, Javier Carlos, Rose M. cis-Bis(1,10-phenanthroline-κ(2) N,N′)bis(pyridin-4-amine-κN (1))ruthenium(II) bis(hexafluoridophosphate) |
| title |
cis-Bis(1,10-phenanthroline-κ(2)
N,N′)bis(pyridin-4-amine-κN
(1))ruthenium(II) bis(hexafluoridophosphate)
|
| title_full |
cis-Bis(1,10-phenanthroline-κ(2)
N,N′)bis(pyridin-4-amine-κN
(1))ruthenium(II) bis(hexafluoridophosphate)
|
| title_fullStr |
cis-Bis(1,10-phenanthroline-κ(2)
N,N′)bis(pyridin-4-amine-κN
(1))ruthenium(II) bis(hexafluoridophosphate)
|
| title_full_unstemmed |
cis-Bis(1,10-phenanthroline-κ(2)
N,N′)bis(pyridin-4-amine-κN
(1))ruthenium(II) bis(hexafluoridophosphate)
|
| title_short |
cis-Bis(1,10-phenanthroline-κ(2)
N,N′)bis(pyridin-4-amine-κN
(1))ruthenium(II) bis(hexafluoridophosphate)
|
| title_sort | cis-bis(1,10-phenanthroline-κ(2)
n,n′)bis(pyridin-4-amine-κn
(1))ruthenium(ii) bis(hexafluoridophosphate) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569179/ https://www.ncbi.nlm.nih.gov/pubmed/23424423 http://dx.doi.org/10.1107/S1600536812051999 |
| work_keys_str_mv | AT camilomarianar cisbis110phenanthrolinek2nnbispyridin4aminekn1rutheniumiibishexafluoridophosphate AT martinsfelipet cisbis110phenanthrolinek2nnbispyridin4aminekn1rutheniumiibishexafluoridophosphate AT maltavaleriars cisbis110phenanthrolinek2nnbispyridin4aminekn1rutheniumiibishexafluoridophosphate AT ellenajavier cisbis110phenanthrolinek2nnbispyridin4aminekn1rutheniumiibishexafluoridophosphate AT carlosrosem cisbis110phenanthrolinek2nnbispyridin4aminekn1rutheniumiibishexafluoridophosphate |