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Poly[bis­(μ(2)-5-{4-[(1H-imidazol-1-yl)meth­yl]phen­yl}tetra­zolato)zinc]

In the title compound, [Zn(C(11)H(9)N(6))(2)](n), the Zn(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmeth­yl)phen­yl]tetra­zolate ligands in a distorted tetra­hedral geometry. The ligands bridge the Zn(II) atoms, leading to the formation of...

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Detalles Bibliográficos
Autor principal: Song, Zhe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569184/
https://www.ncbi.nlm.nih.gov/pubmed/23424428
http://dx.doi.org/10.1107/S1600536812050672
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author Song, Zhe
author_facet Song, Zhe
author_sort Song, Zhe
collection PubMed
description In the title compound, [Zn(C(11)H(9)N(6))(2)](n), the Zn(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmeth­yl)phen­yl]tetra­zolate ligands in a distorted tetra­hedral geometry. The ligands bridge the Zn(II) atoms, leading to the formation of a two-dimensional network parallel to (010). The structure is further stabilized by C—H⋯N, C—H⋯π and π–π [centroid–centroid distance = 3.7523 (11) Å] inter­actions within the network.
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spelling pubmed-35691842013-02-19 Poly[bis­(μ(2)-5-{4-[(1H-imidazol-1-yl)meth­yl]phen­yl}tetra­zolato)zinc] Song, Zhe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(11)H(9)N(6))(2)](n), the Zn(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmeth­yl)phen­yl]tetra­zolate ligands in a distorted tetra­hedral geometry. The ligands bridge the Zn(II) atoms, leading to the formation of a two-dimensional network parallel to (010). The structure is further stabilized by C—H⋯N, C—H⋯π and π–π [centroid–centroid distance = 3.7523 (11) Å] inter­actions within the network. International Union of Crystallography 2013-01-09 /pmc/articles/PMC3569184/ /pubmed/23424428 http://dx.doi.org/10.1107/S1600536812050672 Text en © Zhe Song 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Song, Zhe
Poly[bis­(μ(2)-5-{4-[(1H-imidazol-1-yl)meth­yl]phen­yl}tetra­zolato)zinc]
title Poly[bis­(μ(2)-5-{4-[(1H-imidazol-1-yl)meth­yl]phen­yl}tetra­zolato)zinc]
title_full Poly[bis­(μ(2)-5-{4-[(1H-imidazol-1-yl)meth­yl]phen­yl}tetra­zolato)zinc]
title_fullStr Poly[bis­(μ(2)-5-{4-[(1H-imidazol-1-yl)meth­yl]phen­yl}tetra­zolato)zinc]
title_full_unstemmed Poly[bis­(μ(2)-5-{4-[(1H-imidazol-1-yl)meth­yl]phen­yl}tetra­zolato)zinc]
title_short Poly[bis­(μ(2)-5-{4-[(1H-imidazol-1-yl)meth­yl]phen­yl}tetra­zolato)zinc]
title_sort poly[bis­(μ(2)-5-{4-[(1h-imidazol-1-yl)meth­yl]phen­yl}tetra­zolato)zinc]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569184/
https://www.ncbi.nlm.nih.gov/pubmed/23424428
http://dx.doi.org/10.1107/S1600536812050672
work_keys_str_mv AT songzhe polybism2541himidazol1ylmethylphenyltetrazolatozinc