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Poly[bis(μ(2)-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc]
In the title compound, [Zn(C(11)H(9)N(6))(2)](n), the Zn(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmethyl)phenyl]tetrazolate ligands in a distorted tetrahedral geometry. The ligands bridge the Zn(II) atoms, leading to the formation of...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569184/ https://www.ncbi.nlm.nih.gov/pubmed/23424428 http://dx.doi.org/10.1107/S1600536812050672 |
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author | Song, Zhe |
author_facet | Song, Zhe |
author_sort | Song, Zhe |
collection | PubMed |
description | In the title compound, [Zn(C(11)H(9)N(6))(2)](n), the Zn(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmethyl)phenyl]tetrazolate ligands in a distorted tetrahedral geometry. The ligands bridge the Zn(II) atoms, leading to the formation of a two-dimensional network parallel to (010). The structure is further stabilized by C—H⋯N, C—H⋯π and π–π [centroid–centroid distance = 3.7523 (11) Å] interactions within the network. |
format | Online Article Text |
id | pubmed-3569184 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-35691842013-02-19 Poly[bis(μ(2)-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc] Song, Zhe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(11)H(9)N(6))(2)](n), the Zn(II) atom lies on an inversion center and is coordinated by four N atoms from four 5-[4-(1H-imidazol-1-ylmethyl)phenyl]tetrazolate ligands in a distorted tetrahedral geometry. The ligands bridge the Zn(II) atoms, leading to the formation of a two-dimensional network parallel to (010). The structure is further stabilized by C—H⋯N, C—H⋯π and π–π [centroid–centroid distance = 3.7523 (11) Å] interactions within the network. International Union of Crystallography 2013-01-09 /pmc/articles/PMC3569184/ /pubmed/23424428 http://dx.doi.org/10.1107/S1600536812050672 Text en © Zhe Song 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Song, Zhe Poly[bis(μ(2)-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc] |
title | Poly[bis(μ(2)-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc] |
title_full | Poly[bis(μ(2)-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc] |
title_fullStr | Poly[bis(μ(2)-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc] |
title_full_unstemmed | Poly[bis(μ(2)-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc] |
title_short | Poly[bis(μ(2)-5-{4-[(1H-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc] |
title_sort | poly[bis(μ(2)-5-{4-[(1h-imidazol-1-yl)methyl]phenyl}tetrazolato)zinc] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569184/ https://www.ncbi.nlm.nih.gov/pubmed/23424428 http://dx.doi.org/10.1107/S1600536812050672 |
work_keys_str_mv | AT songzhe polybism2541himidazol1ylmethylphenyltetrazolatozinc |