Di-μ-chlorido-bis­{[2-(di-tert-butyl­phosphan­yl)biphenyl-3-yl-κ(2) C (3),P]palladium(II)} dichloro­methane disolvate

The asymmetric unit of the title compound, [Pd(2)Cl(2)(C(20)H(26)P)(2)]·2CH(2)Cl(2), contains one half-mol­ecule of the palladium complex and a dichloro­methane solvent mol­ecule. In the complex, two Pd(II) atoms are bridged by two Cl atoms, with the other two coordination sites occupied by a C atom...

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Detalles Bibliográficos
Autores principales: Holzapfel, Cedric W., Omondi, Bernard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569185/
https://www.ncbi.nlm.nih.gov/pubmed/23424429
http://dx.doi.org/10.1107/S1600536812051136
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author Holzapfel, Cedric W.
Omondi, Bernard
author_facet Holzapfel, Cedric W.
Omondi, Bernard
author_sort Holzapfel, Cedric W.
collection PubMed
description The asymmetric unit of the title compound, [Pd(2)Cl(2)(C(20)H(26)P)(2)]·2CH(2)Cl(2), contains one half-mol­ecule of the palladium complex and a dichloro­methane solvent mol­ecule. In the complex, two Pd(II) atoms are bridged by two Cl atoms, with the other two coordination sites occupied by a C atom of the biphenyl system and a P atom, resulting in a distorted square-planar coordination geometry of the Pd(II) atom and a cyclo­metallated four-membered ring. The Pd(2)Cl(2) unit is located about an inversion center. The planes of the rings of the biphenyl system make a dihedral angle of 66.36 (11)°.
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spelling pubmed-35691852013-02-19 Di-μ-chlorido-bis­{[2-(di-tert-butyl­phosphan­yl)biphenyl-3-yl-κ(2) C (3),P]palladium(II)} dichloro­methane disolvate Holzapfel, Cedric W. Omondi, Bernard Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Pd(2)Cl(2)(C(20)H(26)P)(2)]·2CH(2)Cl(2), contains one half-mol­ecule of the palladium complex and a dichloro­methane solvent mol­ecule. In the complex, two Pd(II) atoms are bridged by two Cl atoms, with the other two coordination sites occupied by a C atom of the biphenyl system and a P atom, resulting in a distorted square-planar coordination geometry of the Pd(II) atom and a cyclo­metallated four-membered ring. The Pd(2)Cl(2) unit is located about an inversion center. The planes of the rings of the biphenyl system make a dihedral angle of 66.36 (11)°. International Union of Crystallography 2013-01-09 /pmc/articles/PMC3569185/ /pubmed/23424429 http://dx.doi.org/10.1107/S1600536812051136 Text en © Holzapfel and Omondi 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Holzapfel, Cedric W.
Omondi, Bernard
Di-μ-chlorido-bis­{[2-(di-tert-butyl­phosphan­yl)biphenyl-3-yl-κ(2) C (3),P]palladium(II)} dichloro­methane disolvate
title Di-μ-chlorido-bis­{[2-(di-tert-butyl­phosphan­yl)biphenyl-3-yl-κ(2) C (3),P]palladium(II)} dichloro­methane disolvate
title_full Di-μ-chlorido-bis­{[2-(di-tert-butyl­phosphan­yl)biphenyl-3-yl-κ(2) C (3),P]palladium(II)} dichloro­methane disolvate
title_fullStr Di-μ-chlorido-bis­{[2-(di-tert-butyl­phosphan­yl)biphenyl-3-yl-κ(2) C (3),P]palladium(II)} dichloro­methane disolvate
title_full_unstemmed Di-μ-chlorido-bis­{[2-(di-tert-butyl­phosphan­yl)biphenyl-3-yl-κ(2) C (3),P]palladium(II)} dichloro­methane disolvate
title_short Di-μ-chlorido-bis­{[2-(di-tert-butyl­phosphan­yl)biphenyl-3-yl-κ(2) C (3),P]palladium(II)} dichloro­methane disolvate
title_sort di-μ-chlorido-bis­{[2-(di-tert-butyl­phosphan­yl)biphenyl-3-yl-κ(2) c (3),p]palladium(ii)} dichloro­methane disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569185/
https://www.ncbi.nlm.nih.gov/pubmed/23424429
http://dx.doi.org/10.1107/S1600536812051136
work_keys_str_mv AT holzapfelcedricw dimchloridobis2ditertbutylphosphanylbiphenyl3ylk2c3ppalladiumiidichloromethanedisolvate
AT omondibernard dimchloridobis2ditertbutylphosphanylbiphenyl3ylk2c3ppalladiumiidichloromethanedisolvate

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