catena-Poly[μ(2)-iodido-diiodidobis(μ(3)-pyridine-2-thione-κ(3) S:S:S)(μ(2)-pyridine-2-thione-κ(2) S:S)tricopper(I)]

In the title compound, [Cu(3)I(3)(C(5)H(5)NS)(3)](n), a polymeric structure is formed along [100] through bridging iodide and pyridine-2-thione ligands. The metal atoms are engaged in [Cu(3)S(3)] and [Cu(2)S(2)] rings sharing Cu—S edges, with the [Cu(2)S(2)] rings located about inversion centers. Cu...

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Detalles Bibliográficos
Autores principales: Ke, Fang, Wu, Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569186/
https://www.ncbi.nlm.nih.gov/pubmed/23424430
http://dx.doi.org/10.1107/S1600536812052051
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author Ke, Fang
Wu, Wen
author_facet Ke, Fang
Wu, Wen
author_sort Ke, Fang
collection PubMed
description In the title compound, [Cu(3)I(3)(C(5)H(5)NS)(3)](n), a polymeric structure is formed along [100] through bridging iodide and pyridine-2-thione ligands. The metal atoms are engaged in [Cu(3)S(3)] and [Cu(2)S(2)] rings sharing Cu—S edges, with the [Cu(2)S(2)] rings located about inversion centers. Cu(I) atoms bridged by iodide ions exhibit the shortest Cu⋯Cu separation in the polymer [2.8590 (14) Å]. The three independent Cu(I) atoms all display distorted tetra­hedral coordination geometries.
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spelling pubmed-35691862013-02-19 catena-Poly[μ(2)-iodido-diiodidobis(μ(3)-pyridine-2-thione-κ(3) S:S:S)(μ(2)-pyridine-2-thione-κ(2) S:S)tricopper(I)] Ke, Fang Wu, Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(3)I(3)(C(5)H(5)NS)(3)](n), a polymeric structure is formed along [100] through bridging iodide and pyridine-2-thione ligands. The metal atoms are engaged in [Cu(3)S(3)] and [Cu(2)S(2)] rings sharing Cu—S edges, with the [Cu(2)S(2)] rings located about inversion centers. Cu(I) atoms bridged by iodide ions exhibit the shortest Cu⋯Cu separation in the polymer [2.8590 (14) Å]. The three independent Cu(I) atoms all display distorted tetra­hedral coordination geometries. International Union of Crystallography 2013-01-09 /pmc/articles/PMC3569186/ /pubmed/23424430 http://dx.doi.org/10.1107/S1600536812052051 Text en © Ke and Wu 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ke, Fang
Wu, Wen
catena-Poly[μ(2)-iodido-diiodidobis(μ(3)-pyridine-2-thione-κ(3) S:S:S)(μ(2)-pyridine-2-thione-κ(2) S:S)tricopper(I)]
title catena-Poly[μ(2)-iodido-diiodidobis(μ(3)-pyridine-2-thione-κ(3) S:S:S)(μ(2)-pyridine-2-thione-κ(2) S:S)tricopper(I)]
title_full catena-Poly[μ(2)-iodido-diiodidobis(μ(3)-pyridine-2-thione-κ(3) S:S:S)(μ(2)-pyridine-2-thione-κ(2) S:S)tricopper(I)]
title_fullStr catena-Poly[μ(2)-iodido-diiodidobis(μ(3)-pyridine-2-thione-κ(3) S:S:S)(μ(2)-pyridine-2-thione-κ(2) S:S)tricopper(I)]
title_full_unstemmed catena-Poly[μ(2)-iodido-diiodidobis(μ(3)-pyridine-2-thione-κ(3) S:S:S)(μ(2)-pyridine-2-thione-κ(2) S:S)tricopper(I)]
title_short catena-Poly[μ(2)-iodido-diiodidobis(μ(3)-pyridine-2-thione-κ(3) S:S:S)(μ(2)-pyridine-2-thione-κ(2) S:S)tricopper(I)]
title_sort catena-poly[μ(2)-iodido-diiodidobis(μ(3)-pyridine-2-thione-κ(3) s:s:s)(μ(2)-pyridine-2-thione-κ(2) s:s)tricopper(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569186/
https://www.ncbi.nlm.nih.gov/pubmed/23424430
http://dx.doi.org/10.1107/S1600536812052051
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AT wuwen catenapolym2iodidodiiodidobism3pyridine2thionek3sssm2pyridine2thionek2sstricopperi

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