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Tetrabromido[4-(triphenylphosphanyloxy)butyl]tellurium acetonitrile monosolvate
In the title compound, [TeBr(4)(C(22)H(23)OP)]·CH(3)CN, the Te atom exhibits a square-pyramidal coordination with an apical Te—C bond and four basal Te—Br bonds. The conformation of the aliphatic C—C—C—C chain is gauche [torsion angle = −67.7 (8)°]. A weak C—H⋯Br interaction helps to establish the...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569187/ https://www.ncbi.nlm.nih.gov/pubmed/23424431 http://dx.doi.org/10.1107/S1600536812051707 |
Sumario: | In the title compound, [TeBr(4)(C(22)H(23)OP)]·CH(3)CN, the Te atom exhibits a square-pyramidal coordination with an apical Te—C bond and four basal Te—Br bonds. The conformation of the aliphatic C—C—C—C chain is gauche [torsion angle = −67.7 (8)°]. A weak C—H⋯Br interaction helps to establish the conformation. In the crystal, there is a weak secondary bonding interaction [Te⋯N = 3.456 (11) Å] between the Te atom and the N atom of the solvent molecule, which completes a distorted TeNCBr(4) octahedron. Inversion dimers linked by pairs of C—H⋯Br interactions are also observed. |
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