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Tetra­bromido­[4-(triphenyl­phosphanyl­oxy)but­yl]tellurium acetonitrile monosolvate

In the title compound, [TeBr(4)(C(22)H(23)OP)]·CH(3)CN, the Te atom exhibits a square-pyramidal coordination with an apical Te—C bond and four basal Te—Br bonds. The conformation of the aliphatic C—C—C—C chain is gauche [torsion angle = −67.7 (8)°]. A weak C—H⋯Br inter­action helps to establish the...

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Detalles Bibliográficos
Autores principales: Närhi, Sari M., Oilunkaniemi, Raija, Laitinen, Risto S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569187/
https://www.ncbi.nlm.nih.gov/pubmed/23424431
http://dx.doi.org/10.1107/S1600536812051707
Descripción
Sumario:In the title compound, [TeBr(4)(C(22)H(23)OP)]·CH(3)CN, the Te atom exhibits a square-pyramidal coordination with an apical Te—C bond and four basal Te—Br bonds. The conformation of the aliphatic C—C—C—C chain is gauche [torsion angle = −67.7 (8)°]. A weak C—H⋯Br inter­action helps to establish the conformation. In the crystal, there is a weak secondary bonding inter­action [Te⋯N = 3.456 (11) Å] between the Te atom and the N atom of the solvent mol­ecule, which completes a distorted TeNCBr(4) octa­hedron. Inversion dimers linked by pairs of C—H⋯Br inter­actions are also observed.