Dichloridodi-μ(2)-hydroxido-di-μ(3)-oxido-octa­phenyl­tetra­tin(IV) dimethyl sulfoxide disolvate

In the centrosymmetric tetra­nuclear title mol­ecule, [Sn(4)(C(6)H(5))(8)Cl(2)O(2)(OH)(2)]·2C(2)H(6)OS, the two independent tin(IV) atoms show distorted trigonal–bipyramidal SnC(2)O(3) and SnC(2)O(2)Cl coordination geometries. The four tin(IV) atoms are bridged by the hydroxo and oxo ligands, formin...

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Detalles Bibliográficos
Autores principales: Foladi, Shahrbano, Khazaei, Parivash, Attar Gharamaleki, Jafar, Notash, Behrouz, Rofouei, Mohammad Kazem
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3569190/
https://www.ncbi.nlm.nih.gov/pubmed/23424434
http://dx.doi.org/10.1107/S1600536812051744
Descripción
Sumario:In the centrosymmetric tetra­nuclear title mol­ecule, [Sn(4)(C(6)H(5))(8)Cl(2)O(2)(OH)(2)]·2C(2)H(6)OS, the two independent tin(IV) atoms show distorted trigonal–bipyramidal SnC(2)O(3) and SnC(2)O(2)Cl coordination geometries. The four tin(IV) atoms are bridged by the hydroxo and oxo ligands, forming a ladder-like array of three edge-connected Sn(2)O(2) squares. The solvent mol­ecules are linked to the tetra­nuclear mol­ecule via O–H⋯O hydrogen bonds.

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